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Lithium azide

CAS No.
19597-69-4
Chemical Name:
Lithium azide
Synonyms
LITHIUM AZIDE;ution in water;Lthium triazide;lithium triazide;LiN3 (20% in H2O);lithiumazide(li(n3));lithium azide solution;ithium azide, pure, 20% soL;LithiuM Azide (Aqueous Solution);LITHIUM AZIDE ISO 9001:2015 REACH
CBNumber:
CB2739539
Molecular Formula:
LiN3
Molecular Weight:
48.96
MDL Number:
MFCD00041956
MOL File:
19597-69-4.mol
Last updated:2023-05-15 10:43:10

Lithium azide Properties

Melting point decomposes at 115–298℃ [CRC10]
Boiling point 103 °C
Density 1.088 g/mL at 25 °C
solubility soluble in Water
form Liquid
color Clear colorless
Water Solubility g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05]
EPA Substance Registry System Lithium azide (Li(N3)) (19597-69-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H300+H330-H311
Precautionary statements  P280-P301+P310+P330-P302+P352+P312-P304+P340+P310
Hazard Codes  T+
Risk Statements  26/27/28-32
Safety Statements  23-36/37/39-45-36/37-28
RIDADR  UN 3287 6.1/PG 2
WGK Germany  3
HazardClass  4.1
HS Code  28500090

Lithium azide price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 480525 Lithium azide solution 20 wt. % in H2O 19597-69-4 25g $309 2024-03-01 Buy
Sigma-Aldrich 480525 Lithium azide solution 20 wt. % in H2O 19597-69-4 100g $650 2024-03-01 Buy
TRC L469095 LithiumAzide(~20%inWater) 19597-69-4 5g $120 2021-12-16 Buy
TRC L469095 LithiumAzide(~20%inWater) 19597-69-4 25g $275 2021-12-16 Buy
American Custom Chemicals Corporation ING0004395 LITHIUM AZIDE 95.00% 19597-69-4 25G $1200.99 2021-12-16 Buy
Product number Packaging Price Buy
480525 25g $309 Buy
480525 100g $650 Buy
L469095 5g $120 Buy
L469095 25g $275 Buy
ING0004395 25G $1200.99 Buy

Lithium azide Chemical Properties,Uses,Production

Chemical Properties

clear colorless solution

Uses

Lithium azide is the lithium salt of Hydrazoic acid and is used to carry out azidolysis reactions (in Acetonitrile), as well as ring opening reactions of aromatics such as Styrene oxide (S687795).

Purification Methods

Digest ~1g with 15mL of 96% EtOH at 35o, filter and dry it in air at temperatures below 80o. Store it in a cool place and treat it as potentially explosive. Its solubility in H2O is 66.4% at16o, and 20.26% at16o in EtOH. [Hofmann-Bang Acta Chem Scand 11 581 1957, Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 581 1963.]

Lithium azide Preparation Products And Raw materials

Raw materials

Preparation Products

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LITHIUM AZIDE lithiumazide(li(n3)) lithium triazide LITHIUM AZIDE, 20 WT. % SOLUTION IN WATE R Lithium azide, 20% solution in water, pure lithium azide solution Lithium azide,pure,20% solution in water Lithium azide, moistened with ca 10% methanol,99% LithiuM azide, 20 wt.% solution in H2O LithiuM Azide (Aqueous Solution) LithiuM azide solution 20 wt. % in H2O Lthium triazide Lithium azide, 20% Solution in Water ithium azide, pure, 20% soL ution in water LITHIUM AZIDE ISO 9001:2015 REACH Lithium azide, 20% w/w, solution in water LITHIUM AZIDE SOLUTION 20% W/W IN WATER LiN3 (20% in H2O) 19597-69-4 LiN3 C-X Bond Formation (Non-Halogen) Synthetic Reagents Azidation/Diazo Transfer Inorganics Azide SourcesMetal and Ceramic Science Azidation/Diazo TransferChemical Ligation Click Chemistry C-X Bond Formation (Non-Halogen) Lithium Salts Salts Synthetic Reagents