Dicyclohexylchlorophosphine
- CAS No.
- 16523-54-9
- Chemical Name:
- Dicyclohexylchlorophosphine
- Synonyms
- chlorodicyclohexylphosphane;CHLORODICYCLOHEXYLPHOSPHINE;Cy2PCl;orodicycL;98% (C6H11)2PCl;DICYCLOHEXYLCHLOROPHOSPHINE;Dicyclohexylphosphine chloride;Chlorodicyclohexylphosphine 97%;Chlorodicyclohexylphosphine,97%;Chlorodicyclohexylphosphine >
- CBNumber:
- CB3345601
- Molecular Formula:
- C12H22ClP
- Molecular Weight:
- 232.73
- MDL Number:
- MFCD00014294
- MOL File:
- 16523-54-9.mol
- MSDS File:
- SDS
Melting point | 126-128 °C |
---|---|
Boiling point | 165 °C/12 mmHg (lit.) |
Density | 1.054 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | Liquid |
Specific Gravity | 1.054 |
color | Colorless to pale yellow |
Water Solubility | reacts violently |
Sensitive | Air & Moisture Sensitive |
InChIKey | AKJFBIZAEPTXIL-UHFFFAOYSA-N |
CAS DataBase Reference | 16523-54-9(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 14-34 | |||||||||
Safety Statements | 26-27-36/37/39-45-8 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
Dicyclohexylchlorophosphine price More Price(34)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 481408 | Chlorodicyclohexylphosphine 97% | 16523-54-9 | 1g | $83.5 | 2024-03-01 | Buy |
Sigma-Aldrich | 481408 | Chlorodicyclohexylphosphine 97% | 16523-54-9 | 5g | $283 | 2024-03-01 | Buy |
TCI Chemical | C1658 | Chlorodicyclohexylphosphine >97.0%(T) | 16523-54-9 | 1g | $52 | 2024-03-01 | Buy |
TCI Chemical | C1658 | Chlorodicyclohexylphosphine >97.0%(T) | 16523-54-9 | 5g | $226 | 2024-03-01 | Buy |
Alfa Aesar | 033571 | Dicyclohexylchlorophosphine, 98+% | 16523-54-9 | 1g | $128.65 | 2024-03-01 | Buy |
Dicyclohexylchlorophosphine Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
- 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
- 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Uses
Dicyclohexylchlorophosphine is used as pharmaceutical intermediate. It is also used in the synthesis of various phosphines.
Application
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Precautions
Store in cool, dry conditions in well sealed containers. Protect from humidity and water. Store under dry inert gas. It is sensitive to air and moisture. Incompatible with strong oxidizing agents.
Dicyclohexylchlorophosphine Preparation Products And Raw materials
Raw materials
Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 424 | 58 |
Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 516 | 58 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9341 | 55 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 6709 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | forrest.lee@dakenchem.com | China | 15956 | 58 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32686 | 60 |
AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
View Lastest Price from Dicyclohexylchlorophosphine manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-02-23 | Dicyclohexylchlorophosphine
16523-54-9
|
US $59.00-485.00 / g | 25g | 0.98 | 25kg | Shanghai UCHEM Inc. | ||
2023-12-16 | Dicyclohexylchlorophosphine
16523-54-9
|
US $0.00-0.00 / kg | 1kg | 97% | 500kg | XINXIANG RUNYU MATERIAL CO., LTD. | ||
2023-11-01 | Dicyclohexylchlorophosphine
16523-54-9
|
US $0.00-0.00 / kg | 0.1kg | 99.0%min | 200kg | Hangzhou ICH Biofarm Co., Ltd |
- Dicyclohexylchlorophosphine
16523-54-9
- US $59.00-485.00 / g
- 0.98
- Shanghai UCHEM Inc.
- Dicyclohexylchlorophosphine
16523-54-9
- US $0.00-0.00 / kg
- 97%
- XINXIANG RUNYU MATERIAL CO., LTD.
- Dicyclohexylchlorophosphine
16523-54-9
- US $0.00-0.00 / kg
- 99.0%min
- Hangzhou ICH Biofarm Co., Ltd
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