ChemicalBook >> CAS DataBase List >>4-Vinylcyclohexene dioxide

4-Vinylcyclohexene dioxide

CAS No.
106-87-6
Chemical Name:
4-Vinylcyclohexene dioxide
Synonyms
VCD;VCHD;ep-206;ERL 4206;erla-2270;erla-2271;nci-c60135;nci-c60139;ERL(R) 4206;chissonox206
CBNumber:
CB4213606
Molecular Formula:
C8H12O2
Molecular Weight:
140.18
MDL Number:
MFCD00022354
MOL File:
106-87-6.mol
MSDS File:
SDS
Last updated:2023-09-06 17:45:48

4-Vinylcyclohexene dioxide Properties

Melting point -55°C
Boiling point 230-232 °C(lit.)
Density 1.094 g/mL at 25 °C(lit.)
refractive index n20/D 1.477(lit.)
Flash point 225 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Colorless or pale yellow liquid
Water Solubility 154.7g/L(20 ºC)
BRN 106071
Stability Stable. Combustible. Incompatible with strong oxidizing agents, alcohols, amines and other compounds containg an active hydrogen. Hydrolyzes slowly in water.
CAS DataBase Reference 106-87-6(CAS DataBase Reference)
FDA UNII 596C064IG4
Proposition 65 List Vinyl cyclohexene dioxide (4-vinyl-1-cyclohexene diepoxide)
IARC 2B (Vol. Sup 7, 60) 1994
EPA Substance Registry System 4-Vinylcyclohexene diepoxide (106-87-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08
Signal word  Danger
Hazard statements  H301+H311+H331-H351
Precautionary statements  P201-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
Hazard Codes  T
Risk Statements  23/24/25-68/20/21/22-68
Safety Statements  23-24-45
RIDADR  UN 2810 6.1/PG 3
WGK Germany  1
RTECS  RN8640000
HazardClass  6.1(b)
PackingGroup  III

4-Vinylcyclohexene dioxide price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 94956 Vinylcyclohexene dioxide purum, for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 100ml $594 2024-03-01 Buy
Sigma-Aldrich 94956 Vinylcyclohexene dioxide purum, for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 250ml $714 2024-03-01 Buy
Sigma-Aldrich S453005 4-VINYLCYCLOHEXENE DIOXIDE AldrichCPR 106-87-6 250mg $185 2022-05-15 Buy
SynQuest Laboratories 2209-1-08 Vinylcyclohexene dioxide 95% 106-87-6 1g $20 2021-12-16 Buy
Crysdot CD11373324 3-(Oxiran-2-yl)-7-oxabicyclo[4.1.0]heptane 95% 106-87-6 5g $50 2021-12-16 Buy
Product number Packaging Price Buy
94956 100ml $594 Buy
94956 250ml $714 Buy
S453005 250mg $185 Buy
2209-1-08 1g $20 Buy
CD11373324 5g $50 Buy

4-Vinylcyclohexene dioxide Chemical Properties,Uses,Production

Chemical Properties

Vinyl cyclohexene dioxide is a colorless liquid

Chemical Properties

colourless liquid. Combustible.

Uses

Vinylcyclohexene dioxide (VCD) is used to study toxicity as an ovotoxin,and it's also used to understand its mechanisms of toxicity towards ovarian follicles and effects on epithelial differentiation.

Uses

Vinylcyclohexene dioxide (VCD) may be used to study and understand its effect on ovarian follicles and effects on epithelial differentiation.

Uses

As a chemical intermediate and as a reactive diluent for diepoxides and epoxy resins.

Production Methods

VCHD is manufactured by epoxidation of 4-vinylcyclohexene with peroxyacetic acid .

Definition

ChEBI: The diepoxide of 4-vinylcyclohexene.

General Description

Clear colorless liquid. Sets to glass at -67°F. Faint olefinic odor.

Air & Water Reactions

Water soluble. Hydrolyzes slowly in water.

Reactivity Profile

4-VINYLCYCLOHEXENE DIOXIDE reacts with active hydrogen compounds (such as alcohols and amines). . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Hazard

Toxic by ingestion and skin absorption, strong irritant to skin and tissue. Female and male reproductive damage. Possible carcinogen.

Health Hazard

Vinyl cyclohexene dioxide (VCD) is an irritant to the skin, eyes, and respiratory system. It is ovotoxic and carcinogenic in experimental animals.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by unspecified route. Moderately toxic by ingestion and skin contact. Mildly toxic by inhalation. Experimental reproductive effects. Mutation data reported. A severe skin irritant.Combustible when exposed to heat or flame. To fight fire, use water, foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

This material is used as a monomer in the production of epoxy resins for coatings and adhesives; as a chemical intermediate and as a reactive diluent.

Carcinogenicity

4-Vinyl-1-cyclohexene diepoxide is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals.

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Incompatibilities

When heated or in contact with catalysts, epoxides may cause violent polymerization. Epoxides are incompatible with reducing agents and oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May react, possibly violently, with water in the presence of acid and other catalysts. Reacts with alcohols, amines and other active hydrogen compounds. Slowly hydrolyzes in water.

Waste Disposal

Concentrated waste containing no peroxides: discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxides: perforation of a container of the waste from a safe distance followed by open burning.

100-40-3
106-87-6
Synthesis of 4-Vinylcyclohexene dioxide from 4-Vinyl-1-cyclohexene
Global( 153)Suppliers
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Hebei Yanxi Chemical Co., Ltd.
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View Lastest Price from 4-Vinylcyclohexene dioxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Vinylcyclohexene dioxide pictures 2023-09-06 4-Vinylcyclohexene dioxide
106-87-6
US $90.00-20.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
4-Vinylcyclohexene dioxide pictures 2023-09-06 4-Vinylcyclohexene dioxide
106-87-6
US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
4-Vinylcyclohexene dioxide  in stock  Factory  pictures 2020-06-02 4-Vinylcyclohexene dioxide in stock Factory
106-87-6
US $1.00 / KG 1KG TOP 3 Factory in China Top 3 largest production capacity Factory Chemwill Asia Co.,Ltd.
ERL(R) 4206 ERL 4206 4-VINYLCYCLOHEXENE DIOXIDE 4-VINYL-1-CYCLOHEXENE DIEPOXIDE 4-VINYL-1-CYCLOHEXENE DIOXIDE 3-EPOXYETHYL-7-OXABICYCLO [4.1.0] HEPTANE VINYL-4-CYCLOHEXENE DIOXIDE VINYLCYCLOHEXENE DIOXIDE VCHD 1,0]heptane,3-oxiranyl-7-Oxabicyclo[4 1,2-epoxy-4-(epoxyethyl)cyclohexane 1-ethyleneoxy-3,4-epoxycyclohexane 1-vinyl-3-cyclohexenedioxide 3-(1,2-epoxyethyl)-7-oxabicyclo(4.1.0)heptane unoxepoxide206 vinylcyclohexanediepoxide vinylcyclohexanedioxide vinylcyclohexenediepoxide 4-VINYLCYCLOHEXENE DIOXIDE MIXTURE OF & VINYLCYCLOHEXENE DIOXIDE, MIXTURE OF ISOMERS 3-EPOXYETHYL-7-OXABICYCLO[4.1]HEPTANE 99% VINYLCYCLOHEXENE-7,8-EPOXIDE 4-VINYLCYCLOHEXENE DIOXIDE 99% 1,2-epoxy-4-epoxyethylcyclohexane vinylcyclohexane diepoxide 1,2-Epoxy-4-epoxyethylcyclohexane, 3-Epoxyethyl-7-oxabicyclo[4.1.0]heptane 7-oxa-3-oxiranylbicyclo[4.1.0]heptane 1,2-epoxy-2-(epoxyethyl)cyclohexane 3-(Oxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Vinylcyclohexene dioxide ,96% Vinylcyclohexene dioxide,>=96.0% (GC),mixture of iso mers 1-EPOXYETHYL-3.4-EPOXYCYCLOHEXANE 3-(epoxyethyl)-7-oxabicyclo(4.1.0)heptan 3-epoxyethyl-7-oxabicycloheptane 3-oxiranyl-7-oxabicyclo(4.1.0)heptan 3-oxiranyl-7-oxabicyclo(4.1.0)heptane 3-oxiranyl-7-oxabicyclo(4.1.0)heptene 3-oxiranyl-7-oxabicyclo[4.1.0]heptan Vinylcyclohexene dioxid 4-(1,2-epoxyethyl)-7-oxabicyclo(4.1.0)heptane 4-(epoxyethyl)-7-oxabicyclo(4.1.0)heptane 4-vinlycyclohexenedioxide 4-vinyl-1,2-cyclohexenediepoxide 4-vinylcyclohexenediepoxide 7-oxabicyclo[4.1.0]heptane,3-oxiranyl- chissonox206 cyclohexane,1,2-epoxy-4(epoxyethyl) ep-206 erla-2270 erla-2271 nci-c60135 nci-c60139 ucettextilefinish11-74(obs.) 7-Oxabicyclo[4.1.0]heptane,3-(2-oxiranyl)- VINYLCYCLOHEXENE DIOXIDE, MIXTURE OF 4-Vinylcyclohexene dioxide in stock Factory 1-Epoxyethyl-3,4-epoxy-cyclohexan Vinylcyclohexene dioxide purum, for electron microscopy, mixture of isomers, >=96.0% (GC) VCD