ChemicalBook >> CAS DataBase List >>DL-alpha-Methylbenzylamine
DL-alpha-Methylbenzylamine
- CAS No.
- 618-36-0
- Chemical Name:
- DL-alpha-Methylbenzylamine
- Synonyms
- 1-Phenylethanamine;α-Methylbenzylamine;ALPHA-METHYLBENZYLAMINE;-aL;ALPHA-PEA;DL-A-PHENYLETHYLAMINE;DL-1-PHENYLETHYLAMINE;dl-à-methylbenzylamine;(¬(±
- CBNumber:
- CB4365770
- Molecular Formula:
- C8H11N
- Molecular Weight:
- 121.18
- MDL Number:
- MFCD00008069
- MOL File:
- 618-36-0.mol
- MSDS File:
- SDS
Last updated:2023-11-28 16:31:44
| Melting point | -65 °C |
|---|---|
| Boiling point | 185 °C756 mm Hg(lit.) |
| Density | 0.94 g/mL at 25 °C(lit.) |
| vapor pressure | 0.7 hPa (20 °C) |
| refractive index |
n |
| Flash point | 175 °F |
| storage temp. | Store below +30°C. |
| solubility | 42g/l |
| form | Liquid |
| pka | 9.04±0.10(Predicted) |
| color | Clear colorless to light yellow |
| Water Solubility | 4.2 g/100 mL (20 ºC) |
| Sensitive | Air Sensitive |
| Merck | 14,6026 |
| BRN | 636127 |
| Dielectric constant | 4.4（18℃） |
| Stability | Stable, but absorbs carbon dioxide from the air. Store under an inert atmosphere. Incompatible with strong oxidizing agents, carbon dioxide. |
| InChIKey | RQEUFEKYXDPUSK-UHFFFAOYSA-N |
| LogP | 1.31 at 25℃ |
| CAS DataBase Reference | 618-36-0(CAS DataBase Reference) |
| FDA UNII | HZ9DM6B2MT |
| NIST Chemistry Reference | Benzenemethanamine, «alpha»-methyl-, (.+/-.)-(618-36-0) |
| EPA Substance Registry System | Benzenemethanamine, .alpha.-methyl- (618-36-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302+H312-H314 | |||||||||
| Precautionary statements | P270-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 21/22-34 | |||||||||
| Safety Statements | 26-28-36/37/39-45-28A | |||||||||
| RIDADR | UN 2735 8/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | DP5775000 | |||||||||
| F | 10-23 | |||||||||
| Autoignition Temperature | 355 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29214980 | |||||||||
| NFPA 704 |
|
DL-alpha-Methylbenzylamine price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | M31104 | α-Methylbenzylamine 99% | 618-36-0 | 25ml | $68.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | M31104 | α-Methylbenzylamine 99% | 618-36-0 | 100ml | $87.5 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21256 | DL-1-Phenylethylamine forsynthesis | 618-36-0 | 100mL | $38.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21256 | DL-1-Phenylethylamine forsynthesis | 618-36-0 | 500mL | $94.8 | 2024-03-01 | Buy |
| TCI Chemical | M0165 | DL-1-Phenylethylamine >98.0%(GC)(T) | 618-36-0 | 25mL | $22 | 2024-03-01 | Buy |
DL-alpha-Methylbenzylamine Chemical Properties,Uses,Production
Chemical Properties
liquid
Uses
α-Methylbenzylamine can be used as a reactant for the synthesis of dihydro-5H-dibenz[c,e]azepinium salts by reacting with racemic biphenol derivatives.
Uses
Used for synthesis and as an emulsifying agent; used as a resolving agent and chiral intermediate.
Definition
ChEBI: A phenylethylamine that is ethylamine substituted by a phenyl group at position 1.
Synthesis Reference(s)
The Journal of Organic Chemistry, 49, p. 4272, 1984 DOI: 10.1021/jo00196a031
Chemical and Pharmaceutical Bulletin, 36, p. 1529, 1988 DOI: 10.1248/cpb.36.1529
Tetrahedron Letters, 27, p. 3957, 1986 DOI: 10.1016/S0040-4039(00)84883-2
General Description
α-Methylbenzylamine is a nitrogen source that is widely used as a representative substrate to study the chemo-enzymatic kinetic resolution of primary amines.
Flammability and Explosibility
Non flammable
Purification Methods
Dissolve the amine in toluene, dry over NaOH and distil; fraction boiling at 187-188o/atm is collected. Store it under N2 to avoid forming the carbamate and urea. Similarly for the S-(-) enantiomer [2627-86-3]. [Ingersoll Org Synth Coll Vol II 503 1943, Robinson & Snyder Org Synth Coll Vol III 717 1955, Beilstein 12 IV 2424, 2425.]
DL-alpha-Methylbenzylamine Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
Global( 334)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Zhejiang ZETian Fine Chemicals Co. LTD | 18957127338 | stella@zetchem.com | China | 2141 | 58 |
| Standardpharm Co. Ltd. | 86-714-3992388 | overseasales1@yongstandards.com | United States | 14336 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10297 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
View Lastest Price from DL-alpha-Methylbenzylamine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-06-03 | DL-alpha-Methylbenzylamine
618-36-0
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Guanlang Biotechnology Co,.LTD | |
 |
2022-01-23 | DL-alpha-Methylbenzylamine
618-36-0
|
US $10.00 / Kg/Bag | 1Kg/Bag | 99% | 20 Tons | Hebei Zhanyao Biotechnology Co. Ltd | |
 |
2021-07-13 | DL-alpha-Methylbenzylamine
618-36-0
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
-
- DL-alpha-Methylbenzylamine
618-36-0
- US $5.00-2.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co,.LTD
-
- DL-alpha-Methylbenzylamine
618-36-0
- US $10.00 / Kg/Bag
- 99%
- Hebei Zhanyao Biotechnology Co. Ltd
-
- DL-alpha-Methylbenzylamine
618-36-0
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
618-36-0(DL-alpha-Methylbenzylamine)Related Search:
DL-ALPHA-METHYLBENZYLAMINE
Phenoxybenzamine hydrochloride
Diethylstilbestrol
Tyramine
2-Phenylethylamine hydrochloride
Trimethoprim
4-Fluorobenzylamine
(R)-(+)-1-Phenylethylamine
2-Hexenamide, 2-cyano-5-methyl-
Hexanoic acid,3-(aminomethyl)-5-methyl-, (3R)-
1of4
AKOS BBS-00003709
ALPHA-PHENYL ETHYLAMINE
DL(+/-)-ALPHA-METHYLBENZYLAMINE
DL-ALPHA-METHYLBENZYLAMINE
DL-ALPHA-PHENYLETHYLAMINE
DL-ALPHA-PHENETHYLAMINE
DL-A-METHYLBENZYLAMINE
LABOTEST-BB LTBB000514
(±
(.+/-.)-1-Phenethylamine
(+/-)-benzenemethanamin
)-1-Phenethylamine
.alpha.-methyl-,(±)-Benzenemethanamine
?-Methyl-benzylamine
Benzenemethanamine, alpha-methyl-, (±
Benzenemethanamine,-methyl-,-
Benzylamine, alpha-methyl-, (±
Benzylamine, alpha-methyl-, (.+/-.)-
(+/-)-PEA
(R,S)-(+/-)-1-Phenylethylamine
DL-alpha-Methylbenzylamine,99%
α-Methylbenzylamine,(±)-α-Methylbenzylamine, (±)-1-Phenylethylamine
DL-alpha-Methylbenzy
(±)-1-Phenylethylamine, 98+%
(±)-α-Methylbenzylamine, (±)-1-Phenylethylamine
a-Methylbenzenemethanamine
rac-(1R*)-1-Phenylethanamine
rac-(R*)-α-Phenylethanamine
α-phenylethylaMine (DL-phenylethylaMine)
DL-alpha-MethylbenzylaMine, 99% 100GR
DL-alpha-MethylbenzylaMine, 99% 5GR
α-PhenylethylaMine, α-Methyl-benzylaMine
alpha-MethylbenzylaMine, 99 Percent
α-Phenyethylamine
DL-Aminoethylbenzene
DL-Methylbenzenemethanamine
DL-Methyl-benzylamine
α-Methyl-benzylamine
a-Phenylethylamine95%
DL-Phenylethylamine, 98%
DL-1-Phenylethylamine=(-ALPHA-Methylbenzylamine
Benzenemethanamine, .alpha.-methyl-
(n)-1-phenylethylamine
DL-1-Phenylethylamine for synthesis
)-Bay K 8644 (1,4-Dihydro-2,6-dimethyl-5-nitro-4-[2-(trifluoromethyl) phenyl]-3-pyridinecarboxylic Acid, Methyl Ester)
)-trans-4-(2-Pyridinyl)pyrrolidine-3-carboxylic acid dihydrochloride &ge
)-Limonene-d5
)-N-Methyldesethylreboxetine
)-trans-4-(3-Pyridinyl)pyrrolidine-3-carboxylic acid dihydrochloride 99+% (HPLC)
)-Cannabichromene-d9
)-trans-12,13-Epoxy-9(E)-octadecenoic acid methyl ester
)-Cannabichromenic Acid-d9
)-trans-4-(2-Naphthyl)pyrrolidine-3-carboxylic acid hydrochloride &ge
)-Epichlorohydrin 99+.9% (GC)
)-trans-4-(2-Fluorophenyl)pyrrolidine-3-carboxylic acid hydrochloride &ge
)-1,2-Diphenyl-1-[4-[2-(dimethylamino)ethoxy]phenyl]butan-1-ol-d5
)-Juniper Camphor-D6
)-2-Methyl-d3-piperazine-2,3,3,5,5,6,6-d7