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Ammonium formate

Ammonium formate Structure
Ammonium formate structure
CAS No.
540-69-2
Chemical Name:
Ammonium formate
Synonyms
AMMONIUM FORMAT;AMMONIUM FORMIATE;Ammomium formate;HCOONH4 CH5NO2;mravencanamonny;97.0%， for HPLC;Formiate ammonia;AMMONIUM FORMATE;ammmonium formate;formated’ammonium
CBNumber:
CB3140017
Molecular Formula:
CH5NO2
Molecular Weight:
63.06
MDL Number:
MFCD00013103
MOL File:
540-69-2.mol
MSDS File:
SDS
Last updated:2024-04-09 22:15:29
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Ammonium formate Properties

Melting point 119-121 °C (lit.)
Boiling point 103.28°C (rough estimate)
Density 1.26 g/mL at 25 °C (lit.)
vapor pressure 0.033Pa at 25℃
refractive index 1.4164 (estimate)
Flash point 104℃
storage temp. Inert atmosphere,Room Temperature
solubility H2O: 10 M at 20 °C, clear, colorless
form Solid
color White
PH 6.53(1 mM solution);6.5(10 mM solution);6.49(100 mM solution);6.45(1000 mM solution)
Odor Slight formic acid odour
PH Range 6 - 7
Water Solubility soluble
Sensitive Hygroscopic
λmax λ: 260 nm Amax: 0.05
λ: 280 nm Amax: 0.04
Merck 14,523
BRN 3625095
Stability Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
InChIKey VZTDIZULWFCMLS-UHFFFAOYSA-N
LogP -3.34 at 25℃
FDA 21 CFR 573.170
CAS DataBase Reference 540-69-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 3801F9644E
EPA Substance Registry System Ammonium formate (540-69-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  2
RTECS  BQ6650000
F  3-10
TSCA  Yes
HS Code  29151200
Toxicity LD50 orl-mus: 2250 mg/kg ZERNAL 9,332,69
NFPA 704
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Ammonium formate price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 78314 Ammonium formate solution BioUltra, 10?M in H2O 540-69-2 100mL $107 2024-03-01 Buy
Sigma-Aldrich 78314 Ammonium formate solution BioUltra, 10?M in H2O 540-69-2 500mL $373 2024-03-01 Buy
Sigma-Aldrich 70221 Ammonium formate eluent additive for LC-MS, LiChropur?, ≥99.0% 540-69-2 25g $170 2024-03-01 Buy
Sigma-Aldrich 70221 Ammonium formate eluent additive for LC-MS, LiChropur?, ≥99.0% 540-69-2 100g $617 2024-03-01 Buy
Sigma-Aldrich 156264 Ammonium formate reagent grade, 97% 540-69-2 1kg $144 2024-03-01 Buy
Product number Packaging Price Buy
78314 100mL $107 Buy
78314 500mL $373 Buy
70221 25g $170 Buy
70221 100g $617 Buy
156264 1kg $144 Buy

Ammonium formate Chemical Properties,Uses,Production

Description

Ammonium formate is the ammonium salt of formic acid, and is a colorless, hydroscopic, crystalline solid. It can be synthesized through treating ammonium carbonate with 85% formic acid. It is widely used in many organic reactions such as Leuckart reaction which is the reductive amination of aldehydes and ketones. It can also be used as a buffer in HPLC and LC/MS test. Moreover, it is also used in palladium on carbon (Pd/C) reduction of functional group. It can also be used for the preparation of formic acid in situ as well as being used to store formic acid.

References

http://www.orgsyn.org/demo.aspx?prep=CV2P0503
https://www.alfa.com/zh-cn/catalog/014517/
https://en.wikipedia.org/wiki/Ammonium_formate

Description

Ammonium formate, NH4HCO2, is the ammonium salt of formic acid. It is a colorless, hygroscopic, crystalline solid.

Chemical Properties

colourless crystals

Physical properties

White monoclinic deliquescent crystals or granules; density 1.280 g/cm3; melts at 116°C; highly soluble in water (102 g/100 g at 0°C), solubility rapidly increasing with temperature (i.e., 531 g/100 g at 80°C); soluble in liquid ammonia, alcohol and ether.

Uses

Pure ammonium formate decomposes into formamide and water when heated, and this is its primary use in industry. Formic acid can also be obtained by reacting ammonium formate with a dilute acid, and since ammonium formate is also produced from formic acid, it can serve as a way of storing formic acid.
Ammonium formate can also be used in palladium on carbon (Pd / C) reduction of functional groups. In the presence of Pd / C, ammonium formate decomposes to hydrogen, carbon dioxide, and ammonia.
Ammonium formate can be used for reductive amination of aldehydes and ketones (Leuckart reaction)
Ammonium formate can be used as a buffer in high performance liquid chromatography (HPLC), and is suitable for use with liquid chromatography/mass spectrometry (LC/MS). .

Uses

Ammonium formate is widely used in various organic reactions like Leuckart reaction which involves the reductive amination of aldehydes and ketones. It serves as a buffer in high performance liquid chromatography (HPLC) and liquid chromatography-mass spectrometry (LC/MS). It finds application in palladium on carbon (Pd/C) reduction of functional groups. For example, reduction of alkenes to alkanes and formaldehyde to methanol. It is also used to prepare formic acid insitu as well as used to store formic acid by making it as an ammonium salt.

Uses

In chemical analysis, especially to ppt base metals from salts of the "noble" metals.

Definition

ChEBI: The ammonium salt of formic acid.

Reactions

When heated, ammonium formate eliminates water, forming formamide. Upon further heating it forms to HCN and H2O. A side reaction of this is the decomposition of formamide to CO and NH3.

General Description

White solid with a weak odor of ammonia. Sinks and mixes slowly with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Salts, basic, such as Ammonium formate, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Health Hazard

Inhalation causes irritation of nose and throat. Ingestion irritates mouth and stomach. Contact with eyes or skin causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic and irritating ammonia and formic acid gases may form in fire.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by ingestion andintravenous routes. When heated to decomposition itemits toxic fumes of NOx and NH3.

Purification Methods

Heat the solid in NH3 vapour and dry it in a vacuum till the NH3 odour is faint (note that it can evaporate completely in a vacuum). Recrystallise it from absolute EtOH and then keep it in a desiccator over 99% H2SO4 in vacuo. It is very hygroscopic. It exists in two forms, stable needles and less stable plates. It also forms acid salts, i.e. HCO2NH4.3HCO2H and HCO2NH4.HCO2H. [Kensall & Adler J Am Chem Soc 43 1473 1921, Beilstein 2 IV 18.]

Ammonium formate synthesis

5436-21-5
60100-09-6
3438-46-8
67-56-1
540-69-2
Synthesis of Ammonium formate from Acetylacetaldehyde dimethyl acetal and formamide

Ammonium formate Preparation Products And Raw materials

Raw materials

4-Chlorobenzaldehyde Formic acid Ammonia

Preparation Products

3-Azetidinecarboxylic acid 4-(Trifluoromethyl)nicotinic acid (R)-(-)-2-AMINOHEPTANE 5-FLUORO-2-PICOLINIC ACID (1,3,5-TRIMETHYL-1H-PYRAZOL-4-YL)METHYLAMINE
1-N-Boc-3-hydroxyazetidine C-(1-METHYL-PIPERIDIN-2-YL)-METHYLAMINE 4-METHYL-1,3-OXAZOLE-5-CARBOXYLIC ACID 1,2,4-Triazole Citrazinic acid
4-METHYLOXAZOLE-5-CARBONYL CHLORIDE 3,4,5-Trimethoxybenzylamine 5-(AMINOMETHYL)-2,3-DIHYDROBENZO[B]FURAN 4-CHLORO-7-METHYLTHIENO[3,2-D]PYRIMIDINE Teicoplanin A2
3-Chlorobenzylamine DL-alpha-Methylbenzylamine 4-Aminotetrahydropyran 5-CHLORO-1H-INDAZOLE-3-CARBOXYLIC ACID 4-CHLORO-2-METHYLBENZYLAMINE
7-Methylthieno[3,2-d]pyrimidin-4(3H)-one (4S)-HYDROXY-3-METHYL-2-(2-PROPENYL)-2-CYCLOPENTENE-1-ONE 3-(4-Morpholinyl)aniline 5-amino-1H-Indole-2-carboxylic acid ethyl ester 5-Azaindole
(1H-INDAZOL-3-YL)-ACETIC ACID 4-Hydroxy-3-methoxybenzylamine hydrochloride 3-Amino-5-fluoropyridine DL-ALPHA-METHYLBENZYLAMINE Triadimefon
ETHYL 5-AMINO-1H-INDOLE-2-CARBOXYLATE 3,5-Bis(trifluoromethyl)benzylamine 3-Amino-4-methoxybenzoic acid 2,5-Dimethoxybenzylamine

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Ammonium formate Suppliers

Global( 504)Suppliers
Supplier Tel Email Country ProdList Advantage
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Jiangsu Kolod Food Ingredients Co.,Ltd.
+86-518-85110578 +8618805133257 sales3257@jskolod.com China 132 60
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Hebei Dongdu Import and Export Co. LTD 		+86-15333296769 +86-15333296769 manager@cndongdu.com China 71 58
Dorne Chemical Technology co. LTD 		+86-13583358881 +86-18560316533 Ethan@dornechem.com China 294 58
Shandong Juchuang Chemical Co., LTD 		+undefined15030412209 admin@juchuangchem.com China 387 58
airuikechemical co., ltd. 		+undefined86-15315557071 sales02@airuikechemical.com China 994 58
Shaanxi TNJONE Pharmaceutical Co., Ltd 		+8618740459177 sarah@tnjone.com China 941 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Supplier Advantage
Hefei TNJ Chemical Industry Co.,Ltd.
58
Jiangsu Kolod Food Ingredients Co.,Ltd.
60
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Dongdu Import and Export Co. LTD 		58
Dorne Chemical Technology co. LTD 		58
Shandong Juchuang Chemical Co., LTD 		58
airuikechemical co., ltd. 		58
Shaanxi TNJONE Pharmaceutical Co., Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55

Related articles

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  • Ammonium formate, NH4HCO2, is the ammonium salt of formic acid. Ammonium formate is a colorless, hygroscopic, crystalline soli....
  • Nov 22，2019

View Lastest Price from Ammonium formate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ammonium formate pictures 2024-04-30 Ammonium formate
540-69-2
 US $1.00 / g 1g 99% 1000kg Dorne Chemical Technology co. LTD
Ammonium Formate pictures 2024-04-09 Ammonium Formate
540-69-2
 US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
Ammonium Formate pictures 2024-04-05 Ammonium Formate
540-69-2
 US $0.00 / kg 1kg 99% 1000kg Shaanxi TNJONE Pharmaceutical Co., Ltd

Ammonium formate Spectrum

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