9-Anthraceneboronic acid
- CAS No.
- 100622-34-2
- Chemical Name:
- 9-Anthraceneboronic acid
- Synonyms
- Anthracen-9-ylboronic acid;ANTHRACENE-9-BORONIC ACID;9-Anthracenylboronic acid;DKI84;9-Boronoanthracene;9-anthracene-boronic;9-Anthracenylboronic;9-Anthrylboronicacid;9-Anthraceneboronicl;9-AnthraceneboronicAci
- CBNumber:
- CB5142419
- Molecular Formula:
- C14H11BO2
- Molecular Weight:
- 222.05
- MDL Number:
- MFCD03425925
- MOL File:
- 100622-34-2.mol
- MSDS File:
- SDS
| Melting point | 203-250 °C |
|---|---|
| Boiling point | 479.5±28.0 °C(Predicted) |
| Density | 1.26±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| form | Crystalline Solid |
| pka | 8.53±0.30(Predicted) |
| color | White to tan |
| BRN | 3301031 |
| InChI | InChI=1S/C14H11BO2/c16-15(17)14-6-5-12-7-10-3-1-2-4-11(10)8-13(12)9-14/h1-9,16-17H |
| InChIKey | VHHDLIWHHXBLBK-UHFFFAOYSA-N |
| SMILES | C1=C2C(C=C3C(=C2)C=CC=C3)=CC=C1B(O)O |
| CAS DataBase Reference | 100622-34-2(CAS DataBase Reference) |
9-Anthraceneboronic acid price More Price(49)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 684600 | 9-Anthraceneboronic acid ≥95.0% | 100622-34-2 | 250mg | $60.4 | 2023-06-20 | Buy |
| Sigma-Aldrich | 684600 | 9-Anthraceneboronic acid ≥95.0% | 100622-34-2 | 1g | $90 | 2023-06-20 | Buy |
| TCI Chemical | A2328 | 9-Anthraceneboronic Acid (contains varying amounts of Anhydride) >98.0%(HPLC) | 100622-34-2 | 1g | $47 | 2024-03-01 | Buy |
| TCI Chemical | A2328 | 9-Anthraceneboronic Acid (contains varying amounts of Anhydride) >98.0%(HPLC) | 100622-34-2 | 5g | $93 | 2024-03-01 | Buy |
| Alfa Aesar | L19630 | Anthracene-9-boronic acid, 95% | 100622-34-2 | 500mg | $111 | 2021-12-16 | Buy |
9-Anthraceneboronic acid Chemical Properties,Uses,Production
Description
9-Anthraceneboronic acid is a boronic acid compound mainly used as an organic synthesis and reaction reagent. The addition of 9-Anthraceneboronic acid introduces a borate ester bond and an anthracene functional group into ordinary polyvinyl alcohol, which can be used to prepare the composite material poly(vinyl alcohol) anthraceneboronic acid (PVA-ABA), which is suitable for sustainable engineering applications due to its high mechanical strength and toughness, good water resistance, chemical durability, and ease of recycling. It can also be used to prepare stimuli-responsive polymeric materials and highly efficient luminescent materials.
Chemical Properties
Tan solid
Uses
suzuki reaction
Synthesis
9-bromoanthracence (10.0 g, 38.9 mmol) was dissolved in an anhydrous THF solution (500 mL) and stirred at ?78C. Then, 1.6 M n-BuLi (29.3 mL,46.7 mmol) was added. Triethyl borate (9.3 mL, 54.5 mmol) was added to the reaction after 30 min. After the reaction, the solution was acidified with 2 N HCl solution at room temperature and extracted with ethyl acetate and water. The organic layer was dried with anhydrous MgSO4 and filtered. The solution was evaporated. The residue was dissolved in hexane and added to ethyl acetate. The precipitate was filtered and washed with hexane to obtain a beige compound 9-Anthraceneboronic acid (7.70 g, 89 percent).
Purification Methods
Crystallise the boronic acid from dilute HCl (m 180-184o). The disodium salt has m 209-213o. [Beilstein 16 IV 1679.]
9-Anthraceneboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Shaanxi LuyuanBiomedicine Co., LTD | +86-13991827389 +86-13991827389 | sxlysw@sxlysw.com.cn | China | 50 | 58 |
| Shengyan (Shanghai) New Material Co., Ltd. | +86-021-37596312 +8613585706261 | ken@syanchem.com | China | 149 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 6011 | 58 |
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1099 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 18225 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15956 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21689 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9341 | 55 |
View Lastest Price from 9-Anthraceneboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-05-22 | 9-Anthraceneboronic acid
100622-34-2
|
US $5.00 / KG | 1KG | 99% | 100mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-01-23 | Boronic acid,B-9-anthracenyl-
100622-34-2
|
US $0.00 / KG | 1KG | 98.00% | 150KG /month | Shanghai Daken Advanced Materials Co.,Ltd | |
 |
2023-12-23 | 9-Anthraceneboronic acid
100622-34-2
|
US $50.00-1.00 / kg | 1kg | 99% | g-kg-tons,free sample is available | Henan Fengda Chemical Co., Ltd |
-
- 9-Anthraceneboronic acid
100622-34-2
- US $5.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
-
- Boronic acid,B-9-anthracenyl-
100622-34-2
- US $0.00 / KG
- 98.00%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 9-Anthraceneboronic acid
100622-34-2
- US $50.00-1.00 / kg
- 99%
- Henan Fengda Chemical Co., Ltd