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1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN

CAS No.
1498-88-0
Chemical Name:
1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN
Synonyms
NSC 206176;SP 1 (dye);AKOS 90425;1' 3'-DIHYDRO-1' 3' 3'-TRIMETHYL-6-NITR&;6'-Nitro-1,3,3-trimethylindolinobenzopyrylspiran;1,3,3-Trimethylindolino-6-nitrobenzopyrylospirane;1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN;1',3'-dihydro-1',3',3'-trimethyl-6-nitro-spiro(2H;1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN;1,3,3-trimethyl-6'-nitroindole-2-spiro-2'-benzopyran
CBNumber:
CB5493524
Molecular Formula:
C19H18N2O3
Molecular Weight:
322.36
MDL Number:
MFCD00059175
MOL File:
1498-88-0.mol
Last updated:2023-06-08 17:06:38

1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN Properties

Melting point 32°C
Boiling point 460.98°C (rough estimate)
Density 1.2336 (rough estimate)
refractive index 1.6140 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to crystal
pka 2.41±0.40(Predicted)
color Light yellow to Yellow to Green
InChIKey PSXPTGAEJZYNFI-UHFFFAOYSA-N
EWG's Food Scores 1
EPA Substance Registry System Spiro[2H-1-benzopyran-2,2'-[2H]indole], 1',3'-dihydro-1',3',3'-trimethyl-6-nitro- (1498-88-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
RTECS  WG9810000
HS Code  29349990
NFPA 704
0
2 0

1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 273619 1′,3′-Dihydro-1′,3′,3′-trimethyl-6-nitrospiro[2H-1-benzopyran-2,2′-(2H)-indole] 98% 1498-88-0 1g $150 2024-03-01 Buy
TCI Chemical T0366 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran [Photochromic Compound] >98.0%(HPLC)(T) 1498-88-0 1g $71 2024-03-01 Buy
TCI Chemical T0366 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran [Photochromic Compound] >98.0%(HPLC)(T) 1498-88-0 25g $172 2024-03-01 Buy
TRC T796483 1'',3'',3''-Trimethyl-6-nitrospiro[chromene-2,2''-indoline] 1498-88-0 10mg $45 2021-12-16 Buy
AK Scientific 4479AL 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran 1498-88-0 5g $221 2021-12-16 Buy
Product number Packaging Price Buy
273619 1g $150 Buy
T0366 1g $71 Buy
T0366 25g $172 Buy
T796483 10mg $45 Buy
4479AL 5g $221 Buy

1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN Chemical Properties,Uses,Production

Uses

NitroBIPS is used as a photochromic dye which can be incorporated in poly(vinylalcohol)(PVA) by electro-spinning to form PVA-spiropyran nanofibres. It has photo-responsive behaviour that may be useful in optical data storage applications. It can be used to dope liquid crystal to develop a coloured scattering device that is dual responsive and allows the initiation of electrohydrodynamic instabilities(EHDI). Addition of NitroBIPS can modify the transparency from 100% to 16%, providing a shielding effect which can be used for smart window applications. It may also be used to enhance the adhesion property of polystyrene(PS) on the glass substrate by improving the shear strength by a factor of 7.

General Description

1′,3′-Dihydro-1′,3′,3′-trimethyl-6-nitrospiro(2H-1-benzopyran-2,2′-(2H)-indole)(NitroBIPS) is a photochromic biocompatible spiropyran molecule that has six nitro groups positioned at the benzopyran section. It has a colourless leuco spiropyran form(SP) and coloured trans-merocyanine form(MC) that exhibits absorption peaks in the ultraviolet and visible regions respectively. NitroBIPS possesses a higher quantum yield in comparison to other spiropyran molecules and dissolves in a variety of solvents.

Purification Methods

This photochromic dye crystallises from absolute EtOH [Hinnen et al. Bull Soc Chim Fr 2066 1968, Ramesh & Labes J Am Chem Soc 109 3228 1987, Berman et al. J Am Chem Soc 81 5607 1959]. [Beilstein 27 III/IV 1460.]

1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 71)Suppliers
Supplier Tel Email Country ProdList Advantage
Fluoropharm Co., Ltd.
+86-0571-85586753; +8613336034509 sales@fluoropharm.com China 1377 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32686 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
Apeloa Pharmaceutical Co., Ltd.
+86-0571-87635730 +8615858229168 chem1022@hengdian-group.com China 1469 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207 sales@molcore.com China 49739 58

View Lastest Price from 1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN pictures 2019-07-06 1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN
1498-88-0
US $1.00 / kg 1kg 98% 200 Career Henan Chemical Co
1',3'-DIHYDRO-1',3',3'-TRIMETHYL-6-NITRO -SPIRO(2H-1BENZOPYRAN2,2'(2H)INDOLE)98% 1,3,3-Trimethylindolino-6-nitrobenzopyrylospirane 1',3',3'-trimethyl-6-nitroindolene-2-spiro-2-benzopyran 1,3,3-TRIMETHYLINDOLINO-6-NITROBENZOPYRYLOSPIRAN [PHOTOCHROMIC COMPOUND] 98+% 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran [Photochromic Compound] 1,3,3-trimethyl-6'-nitroindole-2-spiro-2'-benzopyran 1,3,3-Trimethyl-6'-nitrospiro[1H-indole-2(3H),2'-[2H][1]benzopyran] 1,3,3-Trimethyl-6'-nitrospiro[1H-indole-2(3H),2'-[2H-1]benzopyran] 1',3',3'-Trimethyl-6-nitrospiro[3-chromene-2,2'-[2H]indole] 1',3',3'-Trimethyl-6-nitrospiro[α-chromene-2,2'-indoline] 6'-Nitro-1,3,3-trimethylspiro[1H-indole-2(3H),2'-[2H-1]benzopyran] 6-Nitro-1',3',3'-trimethylspiro[2H-1-benzopyran-2,2'-indoline] 1,3,3-TriMethylindolino-6'-nitrobenzopyrylospiran  6-Nitro-1',3',3'-trimethylspiro[2H-benzopyran-2,2'-indoline] 6'-Nitro-1,3,3-trimethylspiro[indoline-2,2'-2'H-chromene] NSC 206176 SP 1 (dye) 1',3',3'-trimethyl-6-nitro-spiro[chromene-2,2'-indole] 1',3',3'-trimethyl-6-nitrospiro[chromene-2,2'-indole] 1,3,3-trimethyl-6’-nitroindoline-2-spiro-2’-benzopyran 1,3,3-Trimethyl-6'-nitroindoline-2-spiro-2'-benzopyran 1',3',3'-Trimethyl-6-nitrospiro[2H-1-benzopyran-2,2'-indoline] 6'-Nitro-1,3,3-trimethylindolinobenzopyrylspiran 6-nitro-1’,3’,3’-trimethyl-spiro(2h-1-benzopyran-2’-indoline) Spiro(2H-1-benzopyran-2,2'-indoline), 6-nitro-1',3',3'-trimethyl- Spiro[2H-1-benzopyran-2,2'-[2H]indole], 1',3'-dihydro-1',3',3'-trimethyl-6-nitro- spiro[2h-1-benzopyran-2,2’-[2h]indole],1’,3’-dihydro-1’,3’,3’-trimethyl-6-nitr Spiro[2H-1-benzopyran-2,2'-indoline], 1',3',3'-trimethyl-6-nitro- 1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN 1',3',3'-TRIMETHYL-6-NITROSPIRO[1(2H)-BENZOPYRAN-2,2'-INDOLINE] 1',3'-DIHYDRO-1',3',3'-TRIMETHYL-6-NITROSPIRO[2H-1-BENZOPYRAN-2,2'-(2H)-INDOLE] 1',3'-dihydro-1',3',3'-trimethyl-6-nitro-spiro(2H 1' 3'-DIHYDRO-1' 3' 3'-TRIMETHYL-6-NITR& AKOS 90425 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran [Photochromic Compound]> 1,3,3-TRIMETHYLINDOLINO-6'-NITROBENZOPYRYLOSPIRAN 1,3,3-Trimethylindolino-6'-nitrobenzopyrylospiran [Photochromic Compound] 1’,3’,3’-Trimethyl-6-nitrospiro[chromene-2,2’-indoline 1498-88-0 Photochromic Compounds Spiropyrans (Photochromic) Organic Electronics and Photonics Photochromic and Thermochromic Dyes Photonic and Optical Materials Functional Materials Photochromic Compounds Spiropyrans (Photochromic)