di-tert-butyl diperoxyphthalate

CAS No.
2155-71-7
Chemical Name:
di-tert-butyl diperoxyphthalate
Synonyms
tert-Butyl diperphthalate;Di-tert-butyl peroxyphthalate;di-tert-butyl diperoxyphthalate;Diperoxyphthalic acid di-tert-butyl ester;1,2-Benzenedicarboperoxoic acid di(tert-butyl);1,2-Benzenediperoxycarboxylic acid di(tert-butyl) ester;Benzene-1,2-di(peroxycarboxylic acid)di-tert-butyl ester;1,2-Benzenedicarboperoxoic acid, 1,2-bis(1,1-dimethylethyl) ester
CBNumber:
CB5879485
Molecular Formula:
C16H22O6
Molecular Weight:
310.34228
MDL Number:
MFCD00048239
MOL File:
2155-71-7.mol
Last updated:2023-05-04 15:14:50

di-tert-butyl diperoxyphthalate Properties

Boiling point 370.51°C (rough estimate)
Density 1.1625 (rough estimate)
refractive index 1.4600 (estimate)
EPA Substance Registry System 1,2-Benzenedicarboperoxoic acid, 1,2-bis(1,1-dimethylethyl) ester (2155-71-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315-H335
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

di-tert-butyl diperoxyphthalate Chemical Properties,Uses,Production

Chemical Properties

This peroxide powder with 8.45% active oxygen and 82% purity was mixed 20% in water and showed small pressure rises in the time–pressure assay when using 1 g of igniter. This indicates that this material poses a deflagration hazard.

General Description

Crystalline solid mixed with water. Water lessens the explosion hazard.

Reactivity Profile

Peroxides, such as DI-(TERT-BUTYLPEROXY)PHTHALATE, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness.

Purification Methods

Crystallise the perphthalate from Et2O or pet ether and dry it over H2SO4. The IR has max 1772cm-1 in CCl4. [Milas & Surgemor J Am Chem Soc 68 642 1946, Milas & Kelin J Org Chem 36 2900 1971, Beilstein 9 III 4190, 9 IV 3260.] Potentially EXPLOSIVE.

di-tert-butyl diperoxyphthalate Preparation Products And Raw materials

Raw materials

Preparation Products

di-tert-butyl diperoxyphthalate Suppliers

Global( 3)Suppliers
Supplier Tel Email Country ProdList Advantage
TargetMol Chemicals Inc.
+1-781-999-5354 support@targetmol.com United States 19973 58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051 1027@dideu.com China 9945 58
di-tert-butyl diperoxyphthalate Di-tert-butyl peroxyphthalate 1,2-Benzenedicarboperoxoic acid di(tert-butyl) 1,2-Benzenediperoxycarboxylic acid di(tert-butyl) ester Benzene-1,2-di(peroxycarboxylic acid)di-tert-butyl ester Diperoxyphthalic acid di-tert-butyl ester tert-Butyl diperphthalate 1,2-Benzenedicarboperoxoic acid, 1,2-bis(1,1-dimethylethyl) ester 2155-71-7