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ChemicalBook >> CAS DataBase List >>(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE structure
CAS No.
443965-10-4
Chemical Name:
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms
SF120132;(S)-SIPHOS;(R)-SIPHOS;1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE;N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%;N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS;(S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine;(S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine
CBNumber:
CB6285478
Molecular Formula:
C19H20NO2P
Molecular Weight:
325.34
MDL Number:
MFCD08459340
MOL File:
443965-10-4.mol
Last updated:2023-05-04 15:16:30
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Properties

Melting point 95-96°C
Boiling point 429.6±55.0 °C(Predicted)
alpha -502° (c 0.5, CH2Cl2)
storage temp. -20°C
pka 2.19±0.20(Predicted)
form solid
color white
Sensitive moisture sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  29252900

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-5151 (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS 443965-10-4 100mg $107 2024-03-01 Buy
Strem Chemicals 15-5151 (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (S)-SIPHOS 443965-10-4 500mg $421 2024-03-01 Buy
ChemScene CS-0062402 (S)-SIPHOS 443965-10-4 50mg $88 2021-12-16 Buy
ChemScene CS-0062402 (S)-SIPHOS 443965-10-4 100mg $158 2021-12-16 Buy
Product number Packaging Price Buy
15-5151 100mg $107 Buy
15-5151 500mg $421 Buy
CS-0062402 50mg $88 Buy
CS-0062402 100mg $158 Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Uses,Production

Reaction

  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes. 
Reactions of 443965-10-4_1
Reactions of 443965-10-4_2
Reactions of 443965-10-4_3

Chemical Properties

White to light yellow powder

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

Toluene Hexamethylphosphorous triamide (S)-1,1'-SPIROBIINDANE-7,7'-DIOL

Preparation Products

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers

Global( 35)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 906 58
Career Henan Chemica Co 		+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
CR Corporation Lomited 		fred.wen@crcorporation.cn CHINA 12069 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 50000 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
BeiJing Hwrk Chemicals Limted 0757-86329057 18934348241 sales4.gd@hwrkchemical.com China 14067 55
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6854 65
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 3022 50
Supplier Advantage
Shanghai Arbor Chemical Co., Ltd. 		58
Career Henan Chemica Co 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
CR Corporation Lomited 		58
GIHI CHEMICALS CO.,LIMITED 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
BeiJing Hwrk Chemicals Limted 55
Daicel Chiral Technologies (China)CO.,LTD 65
Tianjin Derchemist Science & Technology Co., Ltd. 50

443965-10-4((11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE)Related Search:

Indene Dimethylamine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE (R)-SIPHOS (S)-SIPHOS (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(S)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98% Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (9CI) N,N-Dimethylphosphoramidousacid (1S)-(2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl) ester (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e. (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (S)-SIPHOS 1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE SF120132 Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (S)-N,N-Dimethyl-1,2,4,5,6,7-hexahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine 443965-10-4 Chiral Phosphine Chiral Spiro Ligand CPN