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PHENYL AZIDE

CAS No.
622-37-7
Chemical Name:
PHENYL AZIDE
Synonyms
Azidobenzene;PHENYL AZIDE;Azido-benzene;triazobenzene;phenylazoimide;Benzene, triazo-;diazobenzeneimide;Phenyl azide solution;Azidobenzene solution;Azidomethane solution - 0.5M solution intert-butyl methyl ether
CBNumber:
CB7390841
Molecular Formula:
C6H5N3
Molecular Weight:
119.12
MDL Number:
MFCD00040895
MOL File:
622-37-7.mol
Last updated:2025-01-27 09:38:02

PHENYL AZIDE Properties

Melting point -27.5°C
Boiling point 212.39°C (rough estimate)
Density 1.0860
vapor density 73.5 at 22-24 mm
refractive index 1.5589
Flash point -12°C
storage temp. -20°C
form liquid
color Pale-yellow oil
BRN 742248
FDA UNII 2G0EH7N6YB
UNSPSC Code 12352200
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H302-H315-H318-H373
Precautionary statements  P210-P280-P301+P312-P303+P361+P353-P305+P351+P338-P314
Hazard Codes  F,Xn
Risk Statements  11-19-48/20/21/22-38
Safety Statements  16
RIDADR  UN 2398 3 / PGII
WGK Germany  3

PHENYL AZIDE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 727490 Azidobenzene solution ~0.5 M in tert-butyl methyl ether, ≥95.0% 622-37-7 10ml $189 2024-03-01 Buy
Sigma-Aldrich 727490 Azidobenzene solution ~0.5 M in tert-butyl methyl ether, ≥95.0% 622-37-7 50ml $347.2 2024-03-01 Buy
Sigma-Aldrich 778583 Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC) 622-37-7 10ml $159 2024-03-01 Buy
Sigma-Aldrich 778583 Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC) 622-37-7 50ml $429 2024-03-01 Buy
TRC B407570 Azidobenzene 622-37-7 100mg $45 2021-12-16 Buy
Product number Packaging Price Buy
727490 10ml $189 Buy
727490 50ml $347.2 Buy
778583 10ml $159 Buy
778583 50ml $429 Buy
B407570 100mg $45 Buy

PHENYL AZIDE Chemical Properties,Uses,Production

Uses

Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8

General Description

Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.

Safety Profile

Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

62-53-3
622-37-7
Synthesis of PHENYL AZIDE from Aniline

PHENYL AZIDE Suppliers

Global( 40)Suppliers
Supplier Tel Email Country ProdList Advantage
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Hangzhou MolCore BioPharmatech Co.,Ltd.
+86-057181025280; +8617767106207 sales@molcore.com China 49734 58
ShenZhen Trendseen Biological Technology Co.,Ltd.
13417589054 trendseenbio@gmail.com China 11681 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
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LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58
Jilin Chinese Academy of Sciences-yanshen Technology
+undefined18143011203 info@chemextension.com China 42056 58
Aladdin Scientific
tp@aladdinsci.com United States 57505 58
DAYANG CHEM (HANGZHOU) CO.,LTD
+8617705817739 info@dycnchem.com China 53881 58
Shaanxi Gulliver Biotechnology Research Co., Ltd 0917-7795337 18409274651 2823986536@qq.com China 3384 58
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44732 61
Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC) Azido-benzene Benzene, triazo- Azidobenzene solution Phenyl azide solution diazobenzeneimide phenylazoimide triazobenzene PHENYL AZIDE Azidobenzene solution ~0.5 M in tert-butyl Methyl ether, >=95.0% Azidomethane solution - 0.5M solution intert-butyl methyl ether Azidobenzene 622-37-7 N3C6H5 Aromatic Azides Azides Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks