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BrettPhos Pd G4

BrettPhos Pd G4 Structure
BrettPhos Pd G4 structure
CAS No.
1599466-83-7
Chemical Name:
BrettPhos Pd G4
Synonyms
BrettPhos Palladacycle Gen. 4;BrettPhos Pd G4;BrettPhos Pd G4c;Gingerol Impurity 5;dicyclohexyl[3,6-dimethoxy-2,4,6-tris(propan-2-yl)-[1,1-;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate-dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine (1:1:1);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min
CBNumber:
CB83148149
Molecular Formula:
C49H68NO5PPds
Molecular Weight:
920.53
MDL Number:
MFCD29917502
MOL File:
1599466-83-7.mol
Last updated:2024-03-18 16:05:02
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BrettPhos Pd G4 Properties

form Powder
color off-white to beige
InChIKey ZTBOMOZSCNBFNQ-UHFFFAOYSA-L

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2843909000

BrettPhos Pd G4 price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 804355 BrettPhos Pd G4 1599466-83-7 250MG $106 2023-06-20 Buy
Sigma-Aldrich 804355 BrettPhos Pd G4 1599466-83-7 1G $326 2023-06-20 Buy
Strem Chemicals 46-0333 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4] 1599466-83-7 250mg $95 2024-03-01 Buy
Strem Chemicals 46-0333 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4] 1599466-83-7 1g $290 2024-03-01 Buy
Strem Chemicals 46-0333 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 4] 1599466-83-7 5g $1158 2024-03-01 Buy
Product number Packaging Price Buy
804355 250MG $106 Buy
804355 1G $326 Buy
46-0333 250mg $95 Buy
46-0333 1g $290 Buy
46-0333 5g $1158 Buy

BrettPhos Pd G4 Chemical Properties,Uses,Production

Reactions

Catalyst used for the N-arylation of amines. Reactions of 1599466-83-7

General Description

BrettPhos Pd G4 is an N-substituted 2-aminobiphenylpalladium methanesulfonate precatalyst. It is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations of using the third generation precatalysts. It is air, moisture and thermally-stable and shows good solubility in common organic solvents. BrettPhos Pd G4 is highly useful in cross-coupling reactions. Some of its excellent features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

BrettPhos Pd G4 synthesis

1070663-78-3
1581285-85-9
1599466-83-7
Synthesis of BrettPhos Pd G4 from 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos and (2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

BrettPhos Pd G4 Preparation Products And Raw materials

Raw materials

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos (2'-Methylamino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

Preparation Products

BrettPhos Pd G4 Suppliers

Global( 92)Suppliers
Supplier Tel Email Country ProdList Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 424 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15956 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32686 60
career henan chemical co 		+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Shaanxi Dideu Medichem Co. Ltd 		+86-029-81138252 +86-18789408387 1057@dideu.com China 2713 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5601 58
Antai Fine Chemical Technology Co.,Limited 		18503026267 info@antaichem.com CHINA 9641 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. 		+86-0532-8699-9256 +8615254267723 kaley@cnfdevelop.com China 1410 58
Wuhan LPBchem Technology Co.,Ltd 		+86-027-63498399 15071314134 LPBchem@163.com CHINA 57 58
Supplier Advantage
XINXIANG RUNYU MATERIAL CO., LTD.
58
Shanghai Daken Advanced Materials Co.,Ltd 		58
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Shaanxi Dideu Medichem Co. Ltd 		58
Richest Group Ltd 		58
Antai Fine Chemical Technology Co.,Limited 		58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 		58
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. 		58
Wuhan LPBchem Technology Co.,Ltd 		58

View Lastest Price from BrettPhos Pd G4 manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
BrettPhos Pd G4 pictures 2024-03-07 BrettPhos Pd G4
1599466-83-7
 US $0.00-0.00 / G 1G 98% 500 XINXIANG RUNYU MATERIAL CO., LTD.
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G4 pictures 2021-06-11 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G4
1599466-83-7
 US $10.00-10.00 / g 1g 0.98 50kg Wuhan LPBchem Technology Co.,Ltd
Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2 pictures 2020-11-16 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2
1599466-83-7
 US $26.00 / KG 1KG 99 100KG Longyan Tianhua Biological Technology Co., Ltd
  • BrettPhos Pd G4 pictures
  • BrettPhos Pd G4
    1599466-83-7
  • US $0.00-0.00 / G
  • 98%
  • XINXIANG RUNYU MATERIAL CO., LTD.

1599466-83-7(BrettPhos Pd G4)Related Search:

Methanesulfonato(triphenylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (PPH3 PD G3) BrettPhos Pd G3 RuPhos Pd G1 Methyl t--Butyl Ether Adduct BrettPhosPalladacycle Palladacycle Gen. 3
t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct
RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1 RuPhos Pd G3 Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) XPhos Pd G2 SPhos Pd G2

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Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.4] BrettPhos Pd G4 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G4 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),[BrettPhos Palladacycle Gen. 4] dicyclohexyl[3,6-dimethoxy-2,4,6-tris(propan-2-yl)-[1,1- BrettPhos Palladacycle Gen. 4 BrettPhos Pd G4c Gingerol Impurity 5 BrettPhos Pd G4 [2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate-dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine (1:1:1) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) 1599466-83-7 C49H68NO5PPdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd