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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) structure

CAS No.: 169689-05-8

Chemical Name:: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

Synonyms: Rostligand;(S,S)-DACH-phenyl ligand;(1S,2S)-(-)-1,2-TROST LIGAND;1S,2S- DHAC-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand;95% (S,S)-DACH-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand 95%;(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp...

CBNumber:: CB9299425

Molecular Formula:: C44H40N2O2P2

Molecular Weight:: 690.76

MDL Number:: MFCD01631274

MOL File:: 169689-05-8.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Properties

Melting point	134-136°C
Boiling point	817.0±65.0 °C(Predicted)
alpha	-134o (C=1 IN METHANOL)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	13.35±0.40(Predicted)
form	Powder
color	white to off-white
optical activity	[α]20/D -134°, c = 1 in methanol

SAFETY

Risk and Safety Statements

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) price More Price(24)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	692794	(S,S)-DACH-phenyl Trost ligand 95%	169689-05-8	250mg	$64.8	2024-03-01	Buy
Sigma-Aldrich	692794	(S,S)-DACH-phenyl Trost ligand 95%	169689-05-8	1g	$374	2024-03-01	Buy
Strem Chemicals	15-0961	(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand	169689-05-8	100mg	$41	2024-03-01	Buy
Strem Chemicals	15-0961	(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand	169689-05-8	500mg	$161	2024-03-01	Buy
Strem Chemicals	15-0961	(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand	169689-05-8	2g	$495	2024-03-01	Buy

Product number	Packaging	Price	Buy
692794	250mg	$64.8	Buy
692794	1g	$374	Buy
15-0961	100mg	$41	Buy
15-0961	500mg	$161	Buy
15-0961	2g	$495	Buy

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties,Uses,Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 169689-05-8_1
Reactions of 169689-05-8_2

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers

Global( 85)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	sale04@alfachem.cn	China	12798	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	peter68@ptchemgroup.com	China	35453	58

Supplier	Advantage
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
PT CHEM GROUP LIMITED	58

View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2021-07-02	(S,S)-DACH-phenyl Trost ligand 169689-05-8	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
	2019-07-11	(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 169689-05-8	US $3.00 / KG	1KG	99%	100kg	Career Henan Chemical Co

(S,S)-DACH-phenyl Trost ligand
169689-05-8
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
169689-05-8
US $3.00 / KG
99%
Career Henan Chemical Co

169689-05-8((1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL))Related Search:

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine

(1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 1,2-Diaminocyclohexane (1S,2S)-(+)-1,2-Diaminocyclohexane

2-Diphenylphosphinobenzaldehyde (+/-)-trans-1,2-Diaminocyclohexane (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) N-(2-AMINO-CYCLOHEXYL)-ACETAMIDE

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(1S,2S)-(-)-1,2-TROST LIGAND (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl) (1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl) (S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand 1S,2S- DHAC-Phenyl Trost Ligand 95% (S,S)-DACH-Phenyl Trost Ligand Rostligand 1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(S,S)-DACH-PhenylTrostLigand (S,S)-DACH-phenyl ligand (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N''-BIS(2''-DIPHENYLPHOSPHINOBENZOYL) TROST LIGAND (S,S)-DACH-phenyl Trost ligand (1S,2S)-(¨C)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl) (S,S)-DACH-phenyl Trost ligand 95% BenzaMide,N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide] (1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e. "N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide] /(S,S)-DACH-Phenyl Trost Ligand" (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),(S,S)-DACH-Phenyl Trost Ligand (1S,2S)-N,N'-1,2-Diaminocyclohexane-bis(2'-diphenylphosphinobenzoyl) N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp... N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide) 169689-05-8 Chiral Nitrogen DACH&Trost Series