ZINC DICHROMATE

Description

Zinc Dichromate is a zinc salt of chromate. It is a kind of versatile and mild reagent for the oxidation of organic compound1. It can be used for oxidation of alcohols, efficient oxidative deprotection of dithioacetals to carbonyl compound, oxidative deamination of alpha-aminophosphonates and amines, oxidation of alpha-hydroxyphosphonates into alpha-ketophosphatates, one-pot synthesis of thiosulfonates from Thiols as well as oxidation of sulfides to sulfoxides. It can also be used for the manufacturing the protective films with anti-corrosion property.

Referrence

• Firouzabadi, H., et al. "Chromium(VI) Based Oxidants; II 1. Zinc Dichromate Trihydrate: A Versatile and Mild Reagent for the Oxidation of Organic Compounds." Synthesis 1986.04(1986):285-288.
• Feizi, N., H. Hassani, and M. Hakimi. "Heterogeneous Method for the Oxidation of Alcohols under Mild Conditions with Zinc Dichromate Adsorbed on Alumina." Cheminform 37.16(2006):2084-2086.
• Firouzabadi, Habib, et al. "Immediate and Efficient Oxidative Deprotection of Dithioacetals to Carbonyl Compounds by Zinc Dichromate Trihydrate (ZnCr2O7×3H2O)." Cheminform 35.41(2004):1967-1972.
• Sobhani, Sara, and M. F. Maleki. "ChemInform Abstract: Oxidative Deamination of α‐Aminophosphonates and Amines by Zinc Dichromate Trihydrate (ZnCr2O7•3H2O) under Solvent‐Free Conditions at Room Temperature. " Cheminform 41.24(2010):383-386.
• Habib Firouzabadi et al. "ChemInform Abstract: High Yield Preparation of α-Ketophosphonates by Oxidation of α-Hydroxyphosphonates with Zinc Dichromate Trihydrate (ZnCr2O7×3H2O) under Solvent-Free Conditions. " Cheminform 32.40(2001):no-no.
• Sobhani, Sara, S. Aryanejad, and M. F. Maleki. "Zinc Dichromate Trihydrate (ZnCr2O7×3H2O) as an Efficient Reagent for the One-Pot Synthesis of Thiosulfonates from Thiols." Synlett 2011.03(2011):319-322.
• Hassani, H. "ChemInform Abstract: Immediate Oxidation of Sulfides to Sulfoxides with Zinc Dichromate Trihydrate under Solvent Free Condition." Cheminform 40.39(2009):1012-1014.
• Farr, J. P. G., and S. V. Kulkarni. "The Chromate and Dichromate Passivation of Zinc." Transactions of the Imf 44.1(1966):21-26.