1,2-디메톡시벤젠

1,2-디메톡시벤젠
1,2-디메톡시벤젠 구조식 이미지
카스 번호:
91-16-7
한글명:
1,2-디메톡시벤젠
동의어(한글):
1,2-디메톡시벤젠;베라트롤
상품명:
1,2-Dimethoxybenzene
동의어(영문):
VERATROLE;Benzene, 1,2-dimethoxy-;VERATROL;Veretrole;ODMB;Synthol;O-DIMETHOXYBENZENE;1,2-Dimethoxybenzol;GUAIACOL METHYL ETHER;CATECHOL DIMETHYL ETHER
CBNumber:
CB5144392
분자식:
C8H10O2
포뮬러 무게:
138.16
MOL 파일:
91-16-7.mol
MSDS 파일:
SDS

1,2-디메톡시벤젠 속성

녹는점
15 °C(lit.)
끓는 점
206-207 °C(lit.)
밀도
1.084 g/mL at 25 °C(lit.)
증기압
0.63 hPa (25 °C)
FEMA
3799 | 1,2-DIMETHOXYBENZENE
굴절률
n20/D 1.533(lit.)
인화점
189 °F
저장 조건
Store below +30°C.
용해도
6.69g/l 불용성
물리적 상태
가루
색상
흰색에서 크림색으로
냄새
디프로필렌 글리콜 중 1.00%. 달콤하고 크리미한 바닐라 페놀릭 머스티
?? ??
바닐라
수용성
알코올, 디에틸 에테르, 아세톤 및 메탄올에 용해됩니다. 물에 약간 용해됩니다.
어는점
21.0 to 23.0 ℃
Merck
14,9956
JECFA Number
1248
BRN
1364621
Dielectric constant
4.0899999999999999
InChIKey
ABDKAPXRBAPSQN-UHFFFAOYSA-N
LogP
1.75-2.22 at 25℃
CAS 데이터베이스
91-16-7(CAS DataBase Reference)
NIST
Benzene, 1,2-dimethoxy-(91-16-7)
EPA
Veratrole (91-16-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 22-20/21/22
안전지침서 36-23-24/25
WGK 독일 1
RTECS 번호 CZ6475000
TSCA Yes
HS 번호 29093090
독성 LD50 in rats, mice (mg/kg): 1360, 2020 orally (Jenner)
기존화학 물질 KE-11034
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
예방조치문구:
NFPA 704
0
2 0

1,2-디메톡시벤젠 MSDS


1,2-Dimethoxybenzene

1,2-디메톡시벤젠 C화학적 특성, 용도, 생산

화학적 성질

Colorless crystals or liquid. Soluble in alcohol and ether; slightly soluble in water.

출처

Reported present in asparagus (raw and cooked), bonito (dried), broccoli (cooked), cauliflower (cooked), cognac, endive, grape, Gruyere de Comte cheese, guava, leek (raw and heated), olive, peas, rhubarb, rice bran and vanilla extract.

용도

1,2-Dimethoxybenzene was used to investigate the electroantennogram response of vine weevil, Otiorhynchus sulcatus to plant volatiles.

제조 방법

Prepared by methylation of pyrocatechol.

정의

ChEBI: A dimethoxybenzene with the methoxy groups at ortho-positions.

일반 설명

1,2-Dimethoxybenzene reacts with Li{N(SO2CF3)2} to yield molecular crystal [Li{N(SO2CF3)2}{C6H4(OCH3)2}2] having solid-state lithium ion conductivity. It is a potential pollinator attractant of the nocturnal moth Hadena bicruris.

Toxicology

Data from 1,2-dimethoxybenzene and read-across analog 1,4-dimethoxybenzene (CAS # 150-78-7) show that 1,2-dimethoxybenzene is not expected to be genotoxic. Data show that there are no safety concerns for 1,2-dimethoxybenzene for skin sensitization under the current declared levels of use. The repeated dose, reproductive, and local respiratory toxicity endpoints were evaluated using the TTC for a Cramer Class I material, and the exposure to 1,2-dimethoxybenzene is below the TTC (0.03 mg/kg/day, 0.03 mg/kg/day, and 1.4 mg/day, respectively). The phototoxicity/photoallergenicity endpoints were evaluated based on UV spectra; 1,2-dimethoxybenzene is not expected to be phototoxic/photoallergenic. For the environmental endpoints, 1,2-dimethoxybenzene is not a PBT as per the IFRA Environmental Standards, and its risk quotients (i.e., PEC/PNEC) for the aquatic environment, based on its current volume of use in Europe and North America, are < 1

Purification Methods

Steam distil veratrole, then fractionally distil it from BaO, CaH2 or Na. Crystallise it from *benzene or low-boiling pet ether at 0o. Fractionally crystallise it from its melt. Store it over anhydrous Na2SO4. [Beilstein 6 IV 5564.]

1,2-디메톡시벤젠 준비 용품 및 원자재

원자재

준비 용품


1,2-디메톡시벤젠 공급 업체

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