N,N'-Bis(salicylidene)-1,3-propanediamine
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N,N'-Bis(salicylidene)-1,3-propanediamine 속성
- 녹는점
- 51-53°C
- 끓는 점
- 466.4±40.0 °C(Predicted)
- 밀도
- 1.11±0.1 g/cm3(Predicted)
- 인화점
- 113 °C
- 저장 조건
- Sealed in dry,Room Temperature
- 용해도
- almost transparency in Toluene
- 물리적 상태
- powder to crystal
- 산도 계수 (pKa)
- 12.55±0.50(Predicted)
- 색상
- Light yellow to Yellow to Green
- BRN
- 2057483
- InChI
- InChI=1S/C17H18N2O2/c20-16-8-3-1-6-14(16)12-18-10-5-11-19-13-15-7-2-4-9-17(15)21/h1-4,6-9,12-13,20-21H,5,10-11H2
- InChIKey
- KLDZYURQCUYZBL-UHFFFAOYSA-N
- SMILES
- C(N=CC1=CC=CC=C1O)CCN=CC1=CC=CC=C1O
- CAS 데이터베이스
- 120-70-7(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험 카페고리 넘버 | 36/37/38 | ||
|---|---|---|---|
| 안전지침서 | 26-36-24/25-22 | ||
| WGK 독일 | 3 | ||
| HS 번호 | 2925.29.9000 |
N,N'-Bis(salicylidene)-1,3-propanediamine C화학적 특성, 용도, 생산
화학적 성질
Light yellow to Yellow to Green powder to crystal용도
N,N′-Bis(salicylidene)-1,3-propanediamine has been used in the synthesis of:- new trinuclear heterometallic Cu(II)-Mn(II) complexes
- mononuclear nickel complex, NiL (LH2 = N,N′-bis(salicylidene)-1,3-diaminopropane)
일반 설명
N,N′-Bis(salicylidene)-1,3-propanediamine is a di-Schiff base ligand.Synthesis
N,N'-Bis(salicylidene)-1,3-propanediamine is prepared by the reaction of 2-Hydroxybenzaldehyde and 1,3-diaminopropane. The specific synthesis steps are as follows:General procedure: This Schiff base was prepared via a condensation reaction in EtOH under hydrothermal conditions using 2-hydroxy-benzaldehyde and 1,3-diaminopropane. 2-Hydroxy-benzaldehyde (0.02 mol, 2.44 g) was dissolved in 40 cm3 of warm EtOH, then 0.01 mol (0.74 g) of 1,3-diaminopropane was added to this solution and heated up to the boiling point. After cooling, yellow crystals were filtered and air-dried. Yield: 92-95%, mp 58 °C (determined by TG). Elemental Anal. Calc. for C17H18N2O2: C, 72.3; H, 6.43; N, 9.92. Found: C, 71.9; H, 6.45; N, 10.47%. λmax = 243 nm, ε = 7045 dm3 mol-1 cm-1 in DMSO, λmax = 242 nm, ε = 7865 dm3 mol-1 cm-1 in MeOH. IR (cm-1): νO-H 2627, νC-H(Ar) 3021-3019, νC-H(aliph) 2929-2862, νC=N 1629, νC=C(ring) 1608, νC-O(phenol) 1274-1151, δC-H(Ar) 762. 1H NMR in d6-DMSO: 13.51 (s) (O-H), 8.60 (s) (-CH=), 7.43 (d) (HAr), 7.32 (t) (HAr), 6.88 (t) (HAr), 3.68 (t) (N-CH2-), 2.01 (p) (-CH2-). 13C NMR in d6-DMSO: 166.6, 161.1, 132.7, 132.1, 119.1, 118.9 (CAr), 116.9 (-C=N), 58.5 (N-CH2-), 31.9 (-CH2-). m/z: 282 [M]+, 161 [HO-C6H4-CH=N-CH2-CH2-CH2]+, 148 [HO-C6H4-CH=N-CH2-CH2]+ (BP), 134 [HO-C6H4-CH=N-CH2]+, 120 [HO-C6H4-CH=N]+, 107 [HO-C6H4-CH2]+, 77 [C6H5]+.
N,N'-Bis(salicylidene)-1,3-propanediamine 준비 용품 및 원자재
원자재
준비 용품
N,N'-Bis(salicylidene)-1,3-propanediamine 공급 업체
글로벌( 91)공급 업체
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