이소펜탄

이소펜탄
이소펜탄 구조식 이미지
카스 번호:
78-78-4
한글명:
이소펜탄
동의어(한글):
이소펜탄;2-메틸부탄;이소펜탄(2-메틸부탄);에틸디메틸메탄;이소아밀수소화물;2-메틸부탄;펜탄;1,1,2-트리메틸에탄;아이소펜탄;아이소펜테인
상품명:
2-Methylbutane
동의어(영문):
ISOPENTANE;Isopentan;methylbutane;3-Methylbutane;JJDW;R 601A;iso-C5H12;iso-Pentan;NSC 119476;2Methylbutan
CBNumber:
CB5854378
분자식:
C5H12
포뮬러 무게:
72.15
MOL 파일:
78-78-4.mol
MSDS 파일:
SDS

이소펜탄 속성

녹는점
-160 °C
끓는 점
30 °C(lit.)
밀도
0.62 g/mL at 25 °C(lit.)
증기 밀도
2.6 (vs air)
증기압
11.17 psi ( 20 °C)
굴절률
n20/D 1.354(lit.)
인화점
−51 °C
저장 조건
2-8°C
용해도
0.048g/L
물리적 상태
액체
산도 계수 (pKa)
>14 (Schwarzenbach et al., 1993)
색상
무색의
냄새
휘발유 같은 냄새
폭발한계
1.3-7.6%(V)
Odor Threshold
1.3ppm
수용성
물, 탄화수소, 오일, 알코올 및 에테르와 혼합됩니다.
최대 파장(λmax)
λ: 192 nm Amax: 1.00
λ: 210 nm Amax: 0.30
λ: 220 nm Amax: 0.07
λ: 240-400 nm Amax: 0.01
BRN
1730723
Henry's Law Constant
(atm?m3/mol): 1.24 at 25 °C (approximate - calculated from water solubility and vapor pressure)
노출 한도
ACGIH TLV: TWA 600 ppm (adopted).
Dielectric constant
1.8(20℃)
안정성
Stable. Extremely flammable. Incompatible with strong oxidizing agents. Vapour-air mixtures explosive in certain proportions. Incompatible with rubber, various plastics. The vapour, being heavier than air, may roll over surfaces and collect in low points. Note low flash point.
LogP
3.4 at 20℃
CAS 데이터베이스
78-78-4(CAS DataBase Reference)
NIST
Butane, 2-methyl-(78-78-4)
EPA
2-Methylbutane (78-78-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F+,Xn,N
위험 카페고리 넘버 12-51/53-65-66-67
안전지침서 9-16-29-33-61-62
유엔번호(UN No.) UN 1265 3/PG 1
WGK 독일 2
RTECS 번호 EK4430000
자연 발화 온도 788 °F
TSCA Yes
위험 등급 3
포장분류 I
HS 번호 29011000
유해 물질 데이터 78-78-4(Hazardous Substances Data)
기존화학 물질 KE-23537
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H224 극인화성 액체 및 증기 인화성 액체 구분 1 위험
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H336 졸음 또는 현기증을 일으킬 수 있음 특정표적장기 독성 물질(1회 노출);마취작용 구분 3 경고 P261, P271, P304+P340, P312,P403+P233, P405, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P331 토하게 하지 마시오.
P403+P233 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.
NFPA 704
4
1 0

이소펜탄 C화학적 특성, 용도, 생산

화학적 성질

2-Methylbutane (isopentane), C5H12, is a flammable liquid and exhibits physical properties very similar to those of pentane. It has been detected in urban air.
2-Methylbutane
2-Methylbutane is an alkane that is butane substituted by a methyl group at position 2. It has a higher BP than butane because, although similarly branched, it has a higher MW. A useful analogy for comparing molecules with the same size of longest chain is that of cylindrical-shaped molecules. It has a role as a refrigerant. Biological samples flash frozen for example with a combination of liquid nitrogen and methylbutane can then be used for storage, cryosection, etc.

물리적 성질

Clear, colorless, watery, very flammable liquid with a pleasant odor. Evaporates quickly when spilled. An odor threshold concentration of 1.3 ppmv was reported by Nagata and Takeuchi (1990).

용도

Isopentane is an organic, branched-chain alkane with five carbon atoms. 2-Methylbutane undergoes catalytic dehydrogenation in the presence of chromia-alumina catalyst to form isoamylenes, which can undergo further dehydrogenation to form isoprene. It may also be used as a solvent in the preparation of trans-Bis(triethylphosphine) (hydroxy carbonyl) (phenyl) platinum(II), a metallacarboxylic acid.

생산 방법

Isopentane is produced by fractional distillation of natural gas liquids and crude oil.

제조 방법

2-Methylbutane was synthesized by liquid-phase catalytic isomerization at 95°C using pentane as raw material.

정의

ChEBI: 2-methylbutane is an alkane that is butane substituted by a methyl group at position 2. It has a role as a refrigerant.

일반 설명

Watery colorless liquid with a gasoline-like odor. Floats on water. Flammable, irritating vapor is produced. Boiling point is 82°F.

공기와 물의 반응

Highly flammable. Insoluble in water.

반응 프로필

2-Methylbutane is a fire and explosion hazard when in contact with oxidizing agents. .

건강위험

Inhalation causes irritation of respiratory tract, cough, mild depression, irregular heartbeat. Aspiration causes severe lung irritation, coughing, pulmonary edema; excitement followed by depression. Ingestion causes nausea, vomiting, swelling of abdomen, headache, depression.

화재위험

Behavior in Fire: Highly volatile liquid. Vapors may explode when mixed with air.

Safety Profile

Mddly toxic and narcotic by inhalation. See also PENTANE. Flammable liquid. A very dangerous fire and explosion hazard when exposed to heat, flame, or oxidzers. Keep away from sparks, heat, or open flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

환경귀착

Photolytic. When synthetic air containing gaseous nitrous acid and 2-methylbutane was exposed to artificial sunlight (λ = 300–450 nm), acetone, acetaldehyde, methyl nitrate, peroxy-acetal nitrate, propyl nitrate, and pentyl nitrate were formed (Cox et al., 1980).
Based upon a photooxidation rate constant of 3.90 x 10-12 cm3/molecule?sec with OH radicals in summer daylight, the atmospheric lifetime is 36 h (Altshuller, 1991). At atmospheric pressure and 300 K, Darnall et al. (1978) reported a rate constant of 3.78 x 10-12 cm3/molecule?sec for the same reaction.
Cox et al. (1980) reported a rate constant of 5.0 x 10-11 cm3/molecule?sec for the reaction of gaseous 2-methylbutane with OH radicals based on a value of 8 x 10-12 cm3/molecule?sec for the reaction of ethylene with OH radicals.
Chemical/Physical. Complete combustion in air produces carbon dioxide and water vapor.
2-Methylbutane will not hydrolyze because it does not contain a hydrolyzable functional group.

Purification Methods

Stir isopentane for several hours in the cold with conc H2SO4 (to remove olefinic impurities), then wash it with H2O, aqueous Na2CO3 and H2O again. Dry it with MgSO4 and fractionally distil it using a Todd column packed with glass helices. Material transparent down to 180nm is obtained by distilling from sodium wire, and passing through a column of silica gel which had previously been dried in place at 350o for 12hours before use. [Potts J Phys Chem 20 809 1952, Beilstein 1 IV 320.]

이소펜탄 준비 용품 및 원자재

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