염화 스트론슘

염화 스트론슘
염화 스트론슘 구조식 이미지
카스 번호:
10476-85-4
한글명:
염화 스트론슘
동의어(한글):
염화스트론슘;염화스트론슘;스트론튬클로라이드
상품명:
Strontium chloride
동의어(영문):
SrCl2;Stronscan-85;Dichlorostrontium;STRONTIUM CHLORIDE;STRONTIUMDICHLORIDE;Strontium Chloride 99%;STRONTIUM (II) CHLORIDE;Strontium chloride,>99%;strontiumchloride(srcl2);Strontium Chloride 99.999%
CBNumber:
CB6250126
분자식:
Cl2Sr
포뮬러 무게:
158.53
MOL 파일:
10476-85-4.mol
MSDS 파일:
SDS

염화 스트론슘 속성

녹는점
874 °C (lit.)
끓는 점
1250 °C/1 atm (lit.)
밀도
3 g/mL at 25 °C (lit.)
굴절률
1.650
인화점
1250°C
저장 조건
2-8°C
용해도
H2O: 용해성
물리적 상태
가루
Specific Gravity
3.052
색상
하얀색
수용성
물에 용해되며 에탄올, 아세톤에 약간 용해됩니다. 암모니아에 불용성.
감도
Hygroscopic
Merck
14,8840
안정성
흡습성
CAS 데이터베이스
10476-85-4(CAS DataBase Reference)
NIST
Strontium dichloride(10476-85-4)
EPA
Strontium chloride (SrCl2) (10476-85-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 37/38-41-36
안전지침서 26-39
WGK 독일 1
RTECS 번호 WK8400000
TSCA Yes
HS 번호 28273985
기존화학 물질 KE-32215
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
3 0

염화 스트론슘 MSDS


Strontium chloride

염화 스트론슘 C화학적 특성, 용도, 생산

개요

Strontium chloride is the inorganic salt consisting of strontium and chloride. In organic synthesis, it can be used as the resource for the manufacturing of other kinds of strontium compound. Compared with the sulfide, it has the advantage of not reacting with oxygen and carbon dioxide, which facilitates industrial handling.
Strontium chloride
Strontium chloride hexahydrate is used in toothpastes for sensitive teeth.It can also be used to reduce the tooth sensitivity through covering the microscopic tubules in the dentin with nerve endings which has been exposed to gum recession. It can be further used as a red coloring agent in pyrotechnics. Recent study has also shown that a novel topical formulation containing strontium chloride can effectively reduce the intensity and duration of cowhage-induced itch. In biological research, it has been successfully used to induce activation of mouse oocytes in nuclear transfer and other experiments, which is important in understanding the mechanisms of fertilization and early embryonic development.
Strontium chloride is not classified as a dangerous material in transport regulations.

화학적 성질

Strontium chloride, SrCl2 is a salt of strontium and chlorine. It is ionic and water-soluble. It is less toxic than barium chloride [CAS: 10361-37-2] BaCl2, though more toxic than calcium chloride CaCl2. It emits a bright red color when heated in a flame. Strontium chloride can be prepared from strontium hydroxide or strontium carbonate reacting with hydrochloric acid. It can also be prepared by the union of the elements, strontium and chlorine.

물리적 성질

Strontium chloride has the formula SrCl2 and the molecular weight of 247.43 g/cm3. It is a typical salt, forming neutral aqueous solutions.
Strontium chloride can be prepared by treating strontium hydroxide or strontium carbonate with hydrochloric acid:
Sr(OH)2+ 2HCl→SrCl2+ 2H2O
SrCO3+ 2HCl→SrCl2+ CO2+H2O
Crystallization from a cold aqueous solution gives the hexahydrate, SrCl2·6H2O. Dehydration of this salt occurs in stages, commencing above 61°C and ending at 320°C, where full dehydration occurs. The dihydrate, SrCl2·2H2O, is a metastable form before the anhydrate begins to form at 200°C. The hydrates formed in solution have one, two or six waters of crystallization.
SrCl2·6H2O is a hexagonal system consisting of colorless long-needle crystals. It loses four crystal waters of hydration at 61.4°C to form plate crystals of SrCl2·2H2O which become the monohydrate at 100°C and anhydrate at 200°C.
Another common hydrate, SrCl2·2H2O, is composed of white, crystalline needles which have a sharp, bitter taste. It can be prepared by fusing SrCO3 with CaCl2 at high temperature and then extracting the melt with water. The solution is then concentrated and then crystallized to form SrCl2·6H2O, which is then dehydrated at 68°C to form the dihydrate.Anhydrous strontium chloride is a colorless crystal or a white powder with a molecular weight of 158.53 g/mol and a density of 3.05 g/cm3. Its melting point is 875°C and its boiling point is 1250°C. It is easily soluble in water but slightly soluble in anhydrous alcohol and acetone. It is not soluble in liquid ammonia.

용도

Strontium chloride are white needles made by fusing calcium chloride with sodium carbonate. It is soluble in water and alcohol. Strontium chloride was a popular halide for making collodion-chloride printing-out emulsions.

정의

strontium chloride: A white compound, SrCl2. The anhydrous salt (cubic; r.d. 3.05; m.p. 872°C; b.p. 1250°C) can be prepared by passing chlorine over heated strontium. It is deliquescent and readily forms the hexahydrate, SrCl2·6H2O (r.d. 2.67).This can be made by neutralizing hydrochloric acid with strontium carbonate, oxide, or hydroxide. Strontium chloride is used for military flares.

제조 방법

Strontium chloride is obtained by dissolving strontium carbonate in concentrated hydrochloric acid. The hexahydrate, SrCl2 · 6H2O [10025-70-4], is formed on crystallizing below 61℃. On dehydration, the hexahydrate dissolves in its water of crystallization at 61℃. After passing through the di- and monohydrate stages, strontium chloride becomes fully dehydrated at 320℃.

일반 설명

Strontium chloride hexahydrate (SrCl2·6H2O) is a hydrated alkaline earth metal chloride. On γ-irradiation at 77°K, it affords a radical having e.s.r. parameters resembling with HO2. Its chlorine electric field gradient (EFG) and chemical shift (CS) tensors have been evaluated by employing solid-state 35/37Cl NMR spectroscopy.

참고 문헌

Papoiu, A. D., et al. "A novel topical formulation containing strontium chloride significantly reduces the intensity and duration of cowhage-induced itch." Acta dermato-venereologica 93.5(2013):520-6.
Minkoff, S, and S. Axelrod. "Efficacy of strontium chloride in dental hypersensitivity. " Journal of Periodontology 58.7(1987):470.
Joyce, James A. "Ornamental colored flame candle." US, US2481019. 1949.
Ma, S. F., et al. "Parthenogenetic activation of mouse oocytes by strontium chloride: a search for the best conditions. " Theriogenology 64.5(2005):1142-57.

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