펜타플루오린화 인(펜타플루오르화 인)

펜타플루오린화 인(펜타플루오르화 인)
펜타플루오린화 인(펜타플루오르화 인) 구조식 이미지
카스 번호:
7647-19-0
한글명:
펜타플루오린화 인(펜타플루오르화 인)
동의어(한글):
펜타플루오로포스포란;펜타플루오린화인(펜타플루오르화인);펜타플루오린화인(펜타플루오르화인)(PHOSPHORUSPENTAFLUORIDE);포스포러스 펜타플루오라이드
상품명:
PHOSPHORUS PENTAFLUORIDE
동의어(영문):
PF5;AURORA KA-1084;pentafluorophosphorus;Pentafluorophosphorane;pentafluoro-phosphoran;PHOSPHORUS (V) FLUORIDE;pentafluoro-Phosphorane;phosphorusfluoride(pf5);POSPHORUS PENTAFLUORIDE;fluoride,penta-phosphoru
CBNumber:
CB6494568
분자식:
F5P
포뮬러 무게:
125.97
MOL 파일:
7647-19-0.mol

펜타플루오린화 인(펜타플루오르화 인) 속성

녹는점
-83°C
끓는 점
-75°C
밀도
5.805g/l
RTECS 번호
TH4070000
인화점
-84.6°C
용해도
reacts with H2O
물리적 상태
가스
색상
무색의
수용성
H2O에서 가수분해되어 결국 H3PO4로 분해됨[MER06]
감도
Moisture Sensitive
Merck
14,7352
노출 한도
TLV-TWA 2.5 mg(F)/m3 (ACGIH and OSHA).
CAS 데이터베이스
7647-19-0(CAS DataBase Reference)
EPA
Pentafluorophosphorane (7647-19-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,T
위험 카페고리 넘버 23-32-34
안전지침서 3/7-9-38-45
유엔번호(UN No.) 2198
위험 참고 사항 Toxic/Corrosive
TSCA Yes
위험 등급 2.3
유해 물질 데이터 7647-19-0(Hazardous Substances Data)
기존화학 물질 KE-28720
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어:
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H330 흡입하면 치명적임 급성 독성 물질 흡입 구분 1, 2 위험 GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
예방조치문구:
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P304+P340 흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P320 긴급히 (…) 처치를 하시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
0 0

펜타플루오린화 인(펜타플루오르화 인) C화학적 특성, 용도, 생산

화학적 성질

colorless gas; nonflammable; fumes strongly in air; high thermal stability; critical temp 144.5°C; critical pressure 3.39MPa; enthalpy of fusion 12.1 kJ/mol; enthalpy of vaporization 17.2 kJ/mol; can be prepared by reaction of PF3 with F2; used as a polymerization catalyst and in electronics industry [AIR87] [HAW93] [MER06] [CRC10] [KIR78]

물리적 성질

Colorless gas; fumes in air; density 5.527g/L; heavier than air, density in air 4.35 (air=1); liquefies at -84.6°C; freezes at -93.8°C; reacts with water.

용도

Phosphorus pentafluoride is usedas a catalyst in polymerization reactions.

일반 설명

PHOSPHORUS PENTAFLUORIDE is a colorless, poisonous, nonflammable, compressed gas with a pungent odor. PHOSPHORUS PENTAFLUORIDE is extremely irritating to skin, eyes and mucus membranes. PHOSPHORUS PENTAFLUORIDE is very toxic by inhalation and can cause pulmonary edema. Toxic and corrosive fumes are generated when PHOSPHORUS PENTAFLUORIDE is exposed to water or steam. Prolonged exposure of the containers to fire or heat may result in their violent rupturing and rocketing. PHOSPHORUS PENTAFLUORIDE is used as a polymerization catalyst.

공기와 물의 반응

Fumes strongly in air, with traces of moisture forming POF3 and HF (corrosive). Decomposed in water or moist air to form phosphoric acid and hydrofluoric Acid, corrosive [Merck 11th ed. 1989].

반응 프로필

PHOSPHORUS PENTAFLUORIDE is a colorless, toxic gas, when exposed to air PHOSPHORUS PENTAFLUORIDE strongly fumes. Vigorous reaction with water or steam leads to decomposition (hydrolysis) producing toxic and corrosive fumes. When heated to decomposition PHOSPHORUS PENTAFLUORIDE emits toxic fumes of fluoride and oxides of phosphorus [Lewis, 3rd ed., 1993, p. 1034].

위험도

Phosphorus pentafluoride is a highly toxic gas. Inhalation can cause severe irritation of mucous membrane and pulmonary edema. It is corrosive to skin and can damage eyes.

건강위험

Phosphorus pentafluoride is highly irritating to the skin, eyes, and respiratory tract. Exposure to this gas can cause pulmonary edema and lung injury. The LC50 value for this compound is not reported. The concentration in air at which it may be lethal to mice over a 10-minute exposure period is estimated to be about 400 ppm (~2050 mg/m3).

화재위험

Some may burn but none ignite readily. Vapors from liquefied gas are initially heavier than air and spread along ground. Some of these materials may react violently with water. Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Safety Profile

A poisonous gas. Violently irritating to skin, eyes, and - mucous membranes. Inhalation may cause pulmonary edema. Reacts with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits highly toxic fumes of Fand POx. See also FLUORIDES.

폐기물 처리

Phosphorus pentafluoride is destroyed by bubbling the gas through a solution of caustic soda (in excess) at a cold temperature. The alkaline mixture is neutralized slowly by dilute HCl and washed down the drain.

펜타플루오린화 인(펜타플루오르화 인) 준비 용품 및 원자재

원자재

준비 용품


펜타플루오린화 인(펜타플루오르화 인) 공급 업체

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Hubei Jusheng Technology Co.,Ltd.
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+86-89586680 +86-13289823923
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Henan Allgreen Chemical Co.,LTD
+86-37155567971 +86-13633837469
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Mainchem Co., Ltd. +86-0592-6210733
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15004251480@139.COM China 4 58
Alfa Aesar 400-6106006
saleschina@alfa-asia.com China 30132 84
Beijing HuaMeiHuLiBiological Chemical 010-56205725
waley188@sohu.com China 12338 58
Huainan Kedi Chemical Factory 0554-2106669
sales1@kedichem.com China 4928 55

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