아폭사이드

아폭사이드
아폭사이드 구조식 이미지
카스 번호:
545-55-1
한글명:
아폭사이드
동의어(한글):
아폭사이드;테파;1,1',1''-포스핀일리다인트리스-아지리딘;1-[비스(아지리딘-1-일)포스포릴]아지리딘;1-아지리딘일 포스핀 옥사이드 (트리스);N,N',N''-트리-1,2-에탄디일포스포르트리아미드;아지리딘일 포스핀 옥사이드;트라이(1-아지리딘일)포스핀 옥사이드;트라이(아지리딘-1-일)포스핀 옥사이드;트라이아지리딘일포스핀 옥사이드;트라이에틸렌이민 포스페이트;트리스(1-아지리딘일)포스핀 옥사이드
상품명:
TEPA
동의어(영문):
tef;tapo;TEPA (pesticide);TRIETHYLENEPHOSPHORAMIDE;tri(aziridin-1-yl)phosphine oxide;1,1’,1"-phosphinylidynetris-aziridin;TEPA;a6366;nsc9717;sk-3818
CBNumber:
CB7239584
분자식:
C6H12N3OP
포뮬러 무게:
173.16
MOL 파일:
545-55-1.mol
MSDS 파일:
SDS

아폭사이드 속성

녹는점
41℃
끓는 점
299℃
밀도
1.47
인화점
135℃
저장 조건
-20°C
용해도
클로로포름(소량으로 용해), 메탄올(약간 용해됨)
물리적 상태
고체
물리적 상태
단단한 모양
산도 계수 (pKa)
2.74±0.20(Predicted)
안정성
안정적인.
IARC
3 (Vol. 9, Sup 7) 1987
EPA
Aziridine, 1,1',1''-phosphinylidynetris- (545-55-1)

안전

유엔번호(UN No.) 2811
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 545-55-1(Hazardous Substances Data)
독성 LD50 orally in male rats: 37 mg/kg (Gaines)
기존화학 물질 KE-05-1291
유해화학물질 필터링 97-1-172
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 아폭사이드 및 이를 1% 이상 함유한 혼합물

아폭사이드 C화학적 특성, 용도, 생산

화학적 성질

Colorless crystals. Soluble in water, alcohol, and ether. Combustible.

용도

Used as insect chemosterilant; in dyeing. Antineoplastic.

일반 설명

An aqueous solution of a colorless crystalline solid. Toxic by skin absorption, ingestion or inhalation. Produces toxic oxides of nitrogen during combustion. Used as a pesticide.

반응 프로필

TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE may react with aqueous solutions of acids or strong bases. Undergoes slow decomposition in water, not considered hazardous. Polymerizes violently at about 255°F. Acid fumes also cause polymerization at ordinary temperatures [USCG, 1999]. May produce highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

건강위험

Inhalation (unlikely unless a heavy mist is formed) causes symptoms similar to those observed after ingestion. Contact with liquid or powder causes irritation of eyes and (on prolonged contact) irritation and burns of skin. Burns are slow to develop and slow to heal. May sensitize on repeated contact. Ingestion causes depression, anorexia, and diarrhea, appearing 2-3 days before death, followed by terminal dyspnea, incoordination, epistaxis, salivation, prostration and cyanosis.

화재위험

Special Hazards of Combustion Products: Phosphoric acid mist may form in fire. Toxic oxides of nitrogen may form.

Safety Profile

Poison by ingestion, skin contact, intravenous, and intraperitoneal routes. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and neoplastigenic data. Human mutation data reported. A corrosive irritant to the skin, eyes, and mucous membranes. When heated to decomposition it emits very toxic fumes of POx and NOx. Used as an acaricide and in the permanentpress treatment of cotton.

아폭사이드 준비 용품 및 원자재

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