가돌리늄

가돌리늄
가돌리늄 구조식 이미지
카스 번호:
7440-54-2
한글명:
가돌리늄
동의어(한글):
가돌리늄;가돌리늄(GADOLINIUM)
상품명:
GADOLINIUM
동의어(영문):
Gd;GD007910;GD007925;GD005105;GD007905;GADOLINIUM;Gadolinium foil;gadolinium atom;GADOLINIUM METAL;Gadolinium chips
CBNumber:
CB7393251
분자식:
Gd
포뮬러 무게:
157.25
MOL 파일:
7440-54-2.mol
MSDS 파일:
SDS

가돌리늄 속성

녹는점
1313 °C (lit.)
끓는 점
3273 °C (lit.)
밀도
7.886 g/mL at 25 °C (lit.)
인화점
3266°C
용해도
soluble in dilute acid solutions
물리적 상태
잉곳 형태
색상
실버 화이트
Specific Gravity
7.898
비저항
126 μΩ-cm, 20°C
수용성
마그네슘과 희석산에 용해됩니다. 물에 불용성.
감도
Air & Moisture Sensitive
Merck
13,4347
노출 한도
ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
안정성
안정적인. 분말은 가연성이 높습니다. 강한 산화제, 할로겐, 산과 호환되지 않습니다. 분말은 물이나 습기와 반응할 수 있습니다.
CAS 데이터베이스
7440-54-2(CAS DataBase Reference)
EPA
Gadolinium (7440-54-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,Xi
위험 카페고리 넘버 15-36/38
안전지침서 43-7/8-26-Neverusewater.
유엔번호(UN No.) UN 3208 4.3/PG 3
WGK 독일 3
RTECS 번호 LW3850000
F 고인화성물질 1
TSCA Yes
위험 등급 8
포장분류 III
HS 번호 2846902015
유해 물질 데이터 7440-54-2(Hazardous Substances Data)
기존화학 물질 KE-05-0661
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H228 인화성 고체 인화성 고체 구분 1
구분 2
위험
경고
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H261 물과 접촉시 인화성가스를 발생시킴 물반응성 물질 및 혼합물 구분 2
구분 3
위험
경고
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P231+P232 불활성 기체 하에서 취급하고, 습기를 방지하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P241 폭발 방지용 장비[전기적/환기/조명/...]을(를) 사용하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
NFPA 704
0
3 0

가돌리늄 C화학적 특성, 용도, 생산

화학적 성질

metal foil, chunks or powder. The powder of gadolinium is highly flammable; incompatible with strong oxidising agents, halogens, acids; and reacts with water or moisture.

물리적 성질

Gadolinium is silvery-white, soft, malleable, and ductile with a metallic luster. It is the secondof what is referred to as the dysprosium, subgroup in the middle of the lanthanide seriesof rare-earths. It tarnishes in air, forming the oxide (Gd2O3) on the surface, which flakes offthe surface, exposing a fresh metal that in turn oxidizes.
Its melting point is 1,313°C, its boiling point is 3,273°C, and its density is 7.90g/cm3.

Isotopes

There are 39 isotopes of gadolinium. Seven of these are stable. They are: Gd-54, which makes up 2.18% of all the gadolinium found in the Earth’s crust; Gd-55,supplying 14.80%; Gd-156, making up 20.47%; Gd-157, constituting 15.56%; and Gd-158, accounting for 24.85%. In addition, there are two isotopes of gadolinium that areradioactive and with such long half-lives that they still exist in the Earth’s crust. They areregarded as stable isotopes along with the other seven. They are Gd-152 (1.08×10+14years), which exists in just 0.20% in abundance, and Gd-160 (1.3×10+21 years), foundin 21.86% abundance.

Origin of Name

Named for the mineral gadolinite, which was named for the French chemist Johann Gadolin.

출처

Gadolinium is the 40th most abundant element on Earth and the sixth most abundant ofthe rare-earths found in the Earth’s crust (6.4 ppm). Like many other rare-earths, gadoliniumis found in monazite river sand in India and Brazil and the beach sand of Florida as well asin bastnasite ores in southern California. Similar to other rare-earths, gadolinium is recoveredfrom its minerals by the ion-exchange process. It is also produced by nuclear fission in atomicreactors designed to produce electricity.

Characteristics

Gadolinium, unlike most of the rare earths in the dysprosium subgroup, reacts slowlywith water, releasing hydrogen. It is strongly magnetic at low temperatures. Two of its stableisotopes (Gd-155 and Gd-157) have the greatest ability of all natural elements to absorb thermalneutrons to control the fission chain reaction in nuclear reactors. However, few of theseisotopes are found in the ores of gadolinium.

용도

Gadolinium’s main use is based on its ability to absorb neutrons, thus making it ideal as aneutron-shielding and neutron-absorbing metal. It is also used as an alloying agent for steel andother metals to make the metals more workable and to be able to withstand low temperatures.
Gadolinium is used in the manufacture of electronics and can be combined with yttriumto make garnets used in microwaves. Gadolinium is used as a catalyst to speed up chemicalreactions, and to activate phosphor compounds in TV screens and cast filaments in electricaldevices. It is also used in high-temperature furnaces. Gadolinium is paramagnetic at normalroom temperatures (weaker than ferromagnetic) and becomes strongly ferromagnetic at verycold temperatures.

정의

A ductile malleable silvery element of the lanthanoid series of metals. It occurs in association with other lanthanoids. Gadolinium is used in alloys, magnets, and in the electronics industry. Symbol: Gd; m.p. 1313°C; b.p. 3266°C; r.d. 7.9 (25°C); p.n. 64; r.a.m. 157.25.

위험도

The halogens of gadolinium are very toxic, and gadolinium nitrate is explosive. As withmost rare-earths, care should be taken not to inhale fumes or ingest particles of gadolinium.

가돌리늄 준비 용품 및 원자재

원자재

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