셀레늄화 아연(셀렌화 아연)

셀레늄화 아연(셀렌화 아연)
셀레늄화 아연(셀렌화 아연) 구조식 이미지
카스 번호:
1315-09-9
한글명:
셀레늄화 아연(셀렌화 아연)
동의어(한글):
셀레늄화아연(셀렌화아연);셀레늄화아연(셀렌화아연)(ZINCSELENIDE);징크 셀레나이드;아연모노셀렌화물;아연셀렌화물;이르트란4
상품명:
Zinc selenide
동의어(영문):
Irtran 4;Zinc selenid;ZINC SELENIDE;Zinc monoselenide;Zinc selenide (ZnSe);Zinc Selenide Powder;Zinc selenide, 99.99%;ZINC SELENIDE, SPECTRO;Zinc selenide/ 99.999%;metel basisZinc selenide
CBNumber:
CB8853039
분자식:
SeZn
포뮬러 무게:
144.35
MOL 파일:
1315-09-9.mol

셀레늄화 아연(셀렌화 아연) 속성

녹는점
1100 °C
밀도
5.42 g/mL at 25 °C(lit.)
용해도
insoluble in H2O; soluble in dilute acid solutions
물리적 상태
불규칙한 플레이크
색상
노란색
Specific Gravity
5.42
수용성
물에 불용성. 묽은 질산에서 분해됩니다.
감도
Air Sensitive
Merck
14,10156
Solubility Product Constant (Ksp)
pKsp: 25.44
노출 한도
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
CAS 데이터베이스
1315-09-9(CAS DataBase Reference)
EPA
Zinc selenide (ZnSe) (1315-09-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N
위험 카페고리 넘버 23/25-33-50/53
안전지침서 20/21-28-45-60-61
유엔번호(UN No.) UN 3283 6.1/PG 2
WGK 독일 3
TSCA Yes
위험 등급 4.3
포장분류 III
HS 번호 28429090
기존화학 물질 KE-35579
유해화학물질 필터링 97-1-134
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 셀레늄 또는 그 화합물과 셀렌화합물을 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H373 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킬 수 있음 특정 표적장기 독성 - 반복 노출 구분 2 경고 P260, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P273 환경으로 배출하지 마시오.
P314 불편함을 느끼면 의학적인 조치·조언을 구하시오.
NFPA 704
0
2 1

셀레늄화 아연(셀렌화 아연) C화학적 특성, 용도, 생산

개요

Zinc selenide (ZnSe) is an II-VI compound semiconductor material with a face-centred cubic crystal structure and excellent physicochemical properties, which has a wide range of transmittance, from 0.5 microns to 19 microns. Zinc selenide is a very good infrared material, mainly used in infrared optics and optoelectronics, and can be used to manufacture window materials, focusing lenses, beam splitters, prisms, and CO2 lasers. Zinc selenide is also commonly used as lenses and windows for CO2 lasers due to its good imaging and thermal shock properties.

화학적 성질

Zinc selenide(ZnSe) is a yellow shiny fine powder that rarely occurs in nature. It is a chemically inert, non-hygroscopic and highly pure material largely found in the mineral stilleite. The transmissivity of zinc selenide is relatively constant over the wavelength range between 0.7 × 10 -6 to 16 × 10 -6 m, making it an excellent choice for flare radiation measurement. ZnSe is highly transparent to the radiation emitted from a flare flame. It is effective in many optical applications owing to its high resistance to thermal shock, stability in virtually all environments and extremely low bulk losses.
Zinc selenide

용도

Zinc selenide (ZnSe) is used as an infrared optical material with wide transmission wavelength range. It is also used as an entrance optic in the new range of "in-ear" clinical thermometers. ZnSe is used as a semiconductor material for thin film devices, and n-type windows layer for thin film heterojunction solar cells. ZnSe activated with tellurium is a scintillator suitable for matching with photodiodes. It is used in x-ray and gamma ray detectors. Zinc selenide films are useful in photovoltaic cells and solar conversion cells. The material can be doped with n-type and p-type doping. It is used to form light-emitting diodes and diode lasers. ZnSe doped with chromium finds use as an IR laser gain medium.

공기와 물의 반응

ZnSe is insoluble in water, but reacts with acids to form toxic hydrogen selenide gas. It can be deposited as a thin film by chemical vapour deposition techniques including MOVPE and vacuum evaporation.

위험도

Fire risk in contact with water or acids.

Synthesis

Zinc Selenide is produced by synthesis from Zinc vapour and H2Se gas, forming as sheets on Graphite susceptors. Another method of producing is a growth from melt under excessive pressure of inert gas (Ar usually).

참고 문헌

[1] HYUN SEON HONG. Facile synthesis and characterization of zinc selenide nanoparticles in aqueous solution at room temperature[J]. Journal of Crystal Growth, 2020, 535: Article 125523. DOI:10.1016/j.jcrysgro.2020.125523.
[2] HILE D D, SWART H C, MOTLOUNG S V, et al. Zinc selenide semiconductor: synthesis, properties and applications[J]. Nanoscale Compound Semiconductors and their Optoelectronics Applications, 2022. DOI:10.1016/b978-0-12-824062-5.00001-4.
[3] https://www.crystran.co.uk/optical-materials/zinc-selenide-znse

셀레늄화 아연(셀렌화 아연) 준비 용품 및 원자재

원자재

준비 용품


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