퍼플루오로옥틸에틸트라이메톡시실레인

퍼플루오로옥틸에틸트라이메톡시실레인
퍼플루오로옥틸에틸트라이메톡시실레인 구조식 이미지
카스 번호:
83048-65-1
한글명:
퍼플루오로옥틸에틸트라이메톡시실레인
동의어(한글):
퍼플루오로옥틸에틸트라이메톡시실레인;(HEPTADECAFLUORO-1,1,2,2-TETRAHYDRODECYL)트리메톡시실란
상품명:
1H,1H,2H,2H-Perfluorodecyltrimethoxysilane
동의어(영문):
1H,1H,2H,2H-PERFLUORODECYLTRIMETHOXYSILANE;TriMethoxy(1H,1H,2H,2H-heptadecafluorodecyl)silane;Uvinul3035;KBM 7803,Shin-Etsu;(HEPTADECAFLUORO-1;Fluorinated Alkyl Silane;2-TETRAHYDRODECYL)TRIMETHOXYSILANE;Heptadecafluorodecyltrimethoxysilane;Perfluoro-octylethyl trimethoxy silane;2-(Perfluorooctyl)ethyl trimethoxysilane
CBNumber:
CB9199653
분자식:
C13H13F17O3Si
포뮬러 무게:
568.3
MOL 파일:
83048-65-1.mol
MSDS 파일:
SDS

퍼플루오로옥틸에틸트라이메톡시실레인 속성

끓는 점
247°C
밀도
1,54 g/cm3
굴절률
1.33125
인화점
>65°C
저장 조건
Keep in dark place,Sealed in dry,Room Temperature
물리적 상태
투명한 액체
색상
무색 내지 거의 무색
Specific Gravity
1.54
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChI
InChI=1S/C13H13F17O3Si/c1-31-34(32-2,33-3)5-4-6(14,15)7(16,17)8(18,19)9(20,21)10(22,23)11(24,25)12(26,27)13(28,29)30/h4-5H2,1-3H3
InChIKey
HJIMAFKWSKZMBK-UHFFFAOYSA-N
SMILES
[Si](CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(OC)(OC)OC
LogP
7.280 (est)
EPA
Silane, (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)trimethoxy- (83048-65-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 20/21/22-36/37/38-34
안전지침서 26-36/37/39-45-24/25
유엔번호(UN No.) UN 3265 8 / PGIII
WGK 독일 3
위험 참고 사항 Corrosive
TSCA No
HS 번호 29420000
기존화학 물질 KE-18219
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H362 모유를 먹는 아이에게 유해할 수 있음 생식독성 물질,수유 또는 수유기에 미치는 영향 추가 카테고리 P201, P260, P263, P264, P270,P308+P313
H372 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴 특정 표적장기 독성 - 반복 노출 구분 1 위험 GHS hazard pictograms P260, P264, P270, P314, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P202 모든 안전 조치 문구를 읽고 이해하기 전에는 취급하지 마시오.
P263 임신·수유 기간에는 접촉하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.

퍼플루오로옥틸에틸트라이메톡시실레인 C화학적 특성, 용도, 생산

화학적 성질

1H,1H,2H,2H-Perfluorodecyltrimethoxysilane is a silicon-based monomer. It is a clear colorless liquid. It is a fluorinated alkylsilane, properties of low reflective index anti-sticking and reactivity for glass, ceramic etc. Heptadecafluorodecyltrimethoxysilane can be used as an anti-fingerprint agent and coating material for glass products such as advanced mobile phone screens and camera lenses.

용도

Trimethoxy(2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-octadecafluorodecyl)silane (CAS# 83048-65-1) has been used in the preparation of abrasion resistant super-antiwetting nylon surfaces. As an additive, Trimethoxy(2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-octadecafluorodecyl)silane is used to increase the hydrophobicity of the surfaces of carbon nanotube structures.

주요 응용

1H,1H,2H,2H-Perfluorodecyltrimethoxysilane is a raw material in area of anti-reflective coating, release coating, soil-repellent coating.
Coating for electronic products.
It is used for self-cleaning of glass and other products. The low refractive index of fluorosilane can prevent the reflection of light from the substrate.
Hydrophobic and oleophobic treatment of glass or fiber surfaces.
For the preparation of wear-resistant super-moisture-resistant nylon surfaces.
As an additive, it is used to increase the hydrophobicity of the surface of the carbon nanotube structure.

Mechanism of action

The hardness of the coating decreased slightly with the addition of 1H,1H,2H,2H-Perfluorodecyltrimethoxysilane (PFTS), which is probably due to the steric hindrance of long perfluoroalkyl chains affecting the condensation of siloxanes and the reaction between epoxide ring (E) and primary amine (PA). The coated surface becomes hydrophobic with the increasing moral ratio of PFTS/PTMS. The increased hydrophobic property should be due to the increased groups of -CF2 and -CF3, which could reduce the surface energy of the coating. Moreover, the surface energy decreases with the addition of PFTS (C1-C5) since the PFTS tends to migrate towards the surface of the coating gradually and significantly improves the hydrophobicity of the coating. The additional amount of the DTDA and PFTS could help form a hard siloxane skeleton and stabilize the three-dimensional structure, which could benefit its anti-aging performance. Meanwhile, no apparent change in the appearance or color of the coatings was found, indicating a favorable weather resistance performance. PFTS have low-surface energy that can effectively tune the surface energy to achieve wettability changes between superILphilic and ILphobic[1-2].

퍼플루오로옥틸에틸트라이메톡시실레인 준비 용품 및 원자재

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