황산 칼륨

황산 칼륨
황산 칼륨 구조식 이미지
카스 번호:
7646-93-7
한글명:
황산 칼륨
동의어(한글):
황산칼륨;황산칼륨(POTASSIUMHYDROGENSULFATE)
상품명:
Potassium bisulfate
동의어(영문):
POTASSIUM HYDROGEN SULFATE;POTASSIUM BISULPHATE;POTASSIUM HYDROGEN SULPHATE;Kaliumhydrogensulfat;salenixum;Potassium bisuL;POTASSIUM BISULFATE;monopotassiumsulfate;acidpotassiumsulfate;POTASSIUM PESULPHATE
CBNumber:
CB9370612
분자식:
HKO4S
포뮬러 무게:
136.16884
MOL 파일:
7646-93-7.mol

황산 칼륨 속성

녹는점
214 °C(lit.)
끓는 점
decomposes [STR93]
밀도
2.32 g/mL at 25 °C(lit.)
저장 조건
Store at +5°C to +30°C.
용해도
H2O: 1 M at 20 °C, 투명, 무색
물리적 상태
고체
물리적 상태
단단한 모양
색상
하얀색
Specific Gravity
2.322
수소이온지수(pH)
1 (50g/l, H2O, 20℃)
수용성
녹는
감도
Hygroscopic
Merck
14,7613
안정성
안정적인. 수분에 민감합니다.
CAS 데이터베이스
7646-93-7(CAS DataBase Reference)
EPA
Potassium bisulfate (7646-93-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 34-37
안전지침서 26-36/37/39-45
유엔번호(UN No.) UN 2509 8/PG 2
WGK 독일 1
RTECS 번호 TS7200000
F 고인화성물질 3
TSCA Yes
HS 번호 2833 29 80
위험 등급 8
포장분류 II
독성 LD50 orally in Rabbit: 2340 mg/kg
기존화학 물질 KE-32642
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P330+P331 삼켰다면 입을 씻어내시오. 토하게 하려 하지 마시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
3 1

황산 칼륨 C화학적 특성, 용도, 생산

화학적 성질

Potassium bisulfate, also known as potassium hydrogen sulfate and potassium acid sulfate, KHS04 is water soluble, white deliquescent crystals,which melt at 214°C. Potassium bisulfate dissolved in water undergoes ionization to form K+, H+, SO42-. It is used in wine making, fertilizer manufacture, and as a flux and food preservative.

주요 응용

Potassium bisulfate may be used:
As a catalyst for the preparation of butyl paraben from p-hydroxybenzoic acid and n-butyl alcohol.
As a promoter for the synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives via Biginelli reaction in ethylene glycol.
As an acid catalyst for the synthesis of ethyl tert-butyl ether (ETBE) from ethanol and tert-butyl alcohol via reactive distillation.
As a dehydrating agent for the synthesis of pyruvic acid from tartaric acid.

제조 방법

Potassium bisulfate is typically made by heating potassium sulfate (K2SO4) with sulfuric acid. The acid provides the hydrogen needed to convert the salt (K2SO4) to the corresponding acid salt (KHSO4).

일반 설명

Potassium hydrogen sulfate is a colorless crystalline solid with a sulfur odor. It may cause illness from ingestion. If heated to high temperatures it may emit toxic fumes. It is used as flux in analysis of ores and siliceous Compounds.

공기와 물의 반응

Fused salt is deliquescent, Soluble in water, yielding a corrosive acidic solution.

반응 프로필

Acidic salts, such as Potassium bisulfate , are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

건강위험

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

화재위험

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Moderately toxic by ingestion. A corrosive irritant to the skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of SOx and K2O. Can form an explosive mixture. See also SULFATES.

Purification Methods

Crystallise it from H2O (1mL/g) between 100o and 0o. It is also formed when a warm solution of K2SO4 in conc H2SO4 is cooled down.

황산 칼륨 준비 용품 및 원자재

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