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ChemicalBook >> CAS DataBase List >>Boron trifluoride

Boron trifluoride suppliers

Boron trifluoride

CAS:
7637-07-2
MF:
BF3
MW:
67.81

Company Type

Properties

Melting point:
−127 °C(lit.)
Boiling point:
−100 °C(lit.)
Density 
0.87 g/mL at 20 °C
vapor density 
2.38 (21 °C, vs air)
vapor pressure 
>1 mmHg at 20 °C
refractive index 
n20/D 1.38
Flash point:
4°C
storage temp. 
2-8°C
solubility 
soluble in H2O
form 
Liquid
color 
Colorless
Odor
Pungent odor detectable at 1.5 ppm
Water Solubility 
MAY DECOMPOSE
Sensitive 
Moisture Sensitive
Merck 
14,1349
Exposure limits
ACGIH: TWA 0.1 ppm(2.5 mg/m3); Ceiling 0.7 ppm
OSHA: Ceiling 1 ppm(3 mg/m3)
NIOSH: IDLH 25 ppm(250 mg/m3); Ceiling 1 ppm(3 mg/m3)
LogP
1.070 (est)

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS04,GHS05,GHS06
Signal word 
Danger
Hazard statements 
H280-H314-H330
Precautionary statements 
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P410+P403
Hazard Codes 
T+,C,T,F
Risk Statements 
14-26-35-39/23/24/25-24/25-11-67-41-10-37-22
Safety Statements 
9-26-28-36/37/39-45-28A-16
RIDADR 
UN 3286 3/PG 2
WGK Germany 
3
RTECS 
ED2275000
21
Hazard Note 
Corrosive/Toxic
TSCA 
Yes
DOT Classification
2.3, Hazard Zone B (Gas poisonous by inhalation)
HazardClass 
2.3
Toxicity
LC50 inhal (rat) 387 ppm (1070 mg/m3; 1 h)
PEL (OSHA) 1 ppm (3 mg/m3; ceiling)
TLV (ACGIH) 1 ppm (3 mg/m3; ceiling)
IDLA
25 ppm

Use

Boron trifluoride (and organic complexes such as BF3-etherate) are extremel corrosive substances that are destructive to all tissues of the body. Upon contact with moisture in the skin and other tissues, these compounds react to form hydrofluoric acid and fluoroboric acid, which cause severe burns. Boron trifluoride gas is extremely irritating to the skin, eyes, and mucous membranes. Inhalation of boron trifluoride can cause severe irritation and burning of the respiratory tract, difficult breathing, and possibly respiratory failure and death. Exposure of the eyes to BF can cause severe burns and blindness. This compound is not considered to have adequate warning properties. Boron trifluoride has not been found to be carcinogenic or to show reproductive or developmental toxicity in humans. Chronic exposure to boron trifluoride gas can cause respiratory irritation and dama

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