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2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE

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Products Intro: Product Name:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
CAS:24720-64-7
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Products Intro: Product Name:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
CAS:24720-64-7
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CAS:24720-64-7
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Products Intro: Product Name:2-(Triphenylphosphoranylidene)propionaldehyde
CAS:24720-64-7
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Products Intro: Product Name:2-(Triphenylphosphoranylidene)
CAS:24720-64-7
Purity:0.99 Package:1kg,5kg,25kgs,200kgs;bulk

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE manufacturers

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Basic information
Product Name:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
Synonyms:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE;2-(triphenylphosphoranylidene)propionaldehyde, 98 %;2-(triphenylphosphoranylidene);2-(TRIPHENYLPHOSPHOR;1-Formylethylidenetriphenylphosphorane;2-(Triphenylphosphoranylidene)propanal;2-(triphenyl-l5-phosphanylidene)propanal;2-(Triphenylphosphoranylidene)propionaldehyde 98%
CAS:24720-64-7
MF:C21H19OP
MW:318.35
EINECS:
Product Categories:Aldehydes;Building Blocks;C13-C60;Carbonyl Compounds;C-C Bond Formation;Chemical Synthesis;Organic Building Blocks;Synthetic Reagents;Wittig Reagents;C-C Bond Formation;Olefination;Wittig Reagents
Mol File:24720-64-7.mol
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Structure
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Chemical Properties
Melting point 219-221 °C (lit.)
Boiling point 478.5±28.0 °C(Predicted)
density 1.14±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Low Melting Solid
color White to pink to brown
CAS DataBase Reference24720-64-7
Safety Information
Risk Statements 22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Usage And Synthesis
Chemical PropertiesWhite to light beige crystalline powder
UsesReactant for:
  • Preparation of acitretin analogs with antitumor activity
  • Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
  • Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
  • Wittig reactions
  • Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
  • Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH
UsesReactant for:• ;Preparation of acitretin analogs with antitumor activity1• ;Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2• ;Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3• ;Wittig reactions4• ;Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5• ;Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors
Uses2-(Triphenylphosphoranylidene)propionaldehyde is a reagent used in the asymmetric synthesis of hispidanin A via oxidative alkoxylation and stereoselective Diels-Alder reaction. Also acts as a reagent in the stereoselective synthesis of 10-epi-tirandamycin E.
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Preparation Products And Raw materials
Preparation Products2-METHYL-3-[4-METHYL(3,5-OXAZOLYL)]PROP-2-ENAL
Tag:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE(24720-64-7) Related Product Information
Ethyl 2-(triphenylphosphoranylidene)propionate 2-(TRIPHENYLPHOSPHORANYLIDENE)SUCCINIC ANHYDRIDE 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE 2-(TRIPHENYLPHOSPHORANYLIDENE)BUTYRALDEHYDE 1-METHOXYCARBONYLETHYLIDENETRIPHENYLPHOSPHORANE ETHYL 4,4,4-TRIFLUORO-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETOACETATE METHYL 2-[5-(4-CHLOROPHENYL)-2-HYDROXY-3-OXO-2,3-DIHYDROFURAN-2-YL]-2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ACETATE 2-[2-(4-CHLOROPHENYL)-2-OXO-1-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ETHYL]-2-HYDROXY-5-PHENYL-2,3-DIHYDROFURAN-3-ONE ETHYL 2,4-DIOXO-3-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)PENTANOATE SPECS AE-848/33625045 METHYL 2-(2-HYDROXY-3-OXO-5-PHENYL-2,3-DIHYDROFURAN-2-YL)-2-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)ACETATE METHYL 3-OXO-3-[3-(TRIFLUOROMETHYL)PHENYL]-2-(TRIPHENYLPHOSPHORANYLIDENE)PROPANOATE AURORA KA-1174 AURORA KA-1073 SALOR-INT L150010-1EA SALOR-INT L151815-1EA 4-[(4-BROMOPHENYL)(DIPHENYL)PHOSPHORANYLIDENE]-5-METHYL-2-PHENYL-2,4-DIHYDRO-3H-PYRAZOL-3-ONE AURORA KA-1180