2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE manufacturers
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| 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Basic information |
| 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Chemical Properties |
Melting point | 219-221 °C (lit.) | Boiling point | 478.5±28.0 °C(Predicted) | density | 1.14±0.1 g/cm3(Predicted) | storage temp. | Inert atmosphere,Store in freezer, under -20°C | form | Low Melting Solid | color | White to pink to brown | CAS DataBase Reference | 24720-64-7 |
| 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Usage And Synthesis |
Chemical Properties | White to light beige crystalline powder | Uses | Reactant for:
- Preparation of acitretin analogs with antitumor activity
- Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
- Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
- Wittig reactions
- Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
- Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH
| Uses | Reactant for:• ;Preparation of acitretin analogs with antitumor activity1• ;Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2• ;Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3• ;Wittig reactions4• ;Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5• ;Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors | Uses | 2-(Triphenylphosphoranylidene)propionaldehyde is a reagent used in the asymmetric synthesis of hispidanin A via oxidative alkoxylation and stereoselective Diels-Alder reaction. Also acts as a reagent in the stereoselective synthesis of 10-epi-tirandamycin E. |
| 2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Preparation Products And Raw materials |
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