- 4-Pyrrolidinopyridine
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- $0.00 / 1kg
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2022-09-16
- CAS:2456-81-7
- Min. Order: 1kg
- Purity: 98%
- Supply Ability: 1Ton
- 4-Pyrrolidinopyridine
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- $1.10 / 1g
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2021-10-26
- CAS:2456-81-7
- Min. Order: 1g
- Purity: 99.00%
- Supply Ability: 100 Tons Min
- 4-Pyrrolidinopyridine
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- $1.00 / 1KG
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2019-12-31
- CAS: 2456-81-7
- Min. Order: 1KG
- Purity: 95-99%
- Supply Ability: 1ton
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| | 4-Pyrrolidinopyridine Basic information |
| | 4-Pyrrolidinopyridine Chemical Properties |
| Melting point | 54-58 °C(lit.) | | Boiling point | 171-173 °C (20.2527 mmHg) | | density | 1.0628 (rough estimate) | | refractive index | 1.5378 (estimate) | | Fp | >230 °F | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | solubility | methanol: 0.1 g/mL, clear | | pka | 9.58±0.10(Predicted) | | form | Crystalline Mass, Crystals and/or Chunks | | color | White to yellow to light brown | | PH | 10.5 (3g/l, H2O, 21℃) | | Water Solubility | 3 g/L (21 ºC) | | BRN | 472443 | | InChIKey | RGUKYNXWOWSRET-UHFFFAOYSA-N | | CAS DataBase Reference | 2456-81-7(CAS DataBase Reference) |
| | 4-Pyrrolidinopyridine Usage And Synthesis |
| Description | 4-Pyrrolidinopyridine is the pyridine derivative. It can be used as catalyst employed in polymerization reactions or Hypernucleophilic acylation catalyst. For example, it can be used as the catalyst for the geometry-selective (E-selective) acylation of tetrasubstituted α, α'-alkenediols. It can also be used as the ligand in metal complexes such as the Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes. | | Chemical Properties | white to light brown crystalline mass | | Uses | Catalyst employed in polymerization reactions. Ligand in metal complexes. | | Synthesis Reference(s) | Synthetic Communications, 9, p. 251, 1979 DOI: 10.1080/00397917908064147
Synthesis, p. 985, 1988 DOI: 10.1055/s-1988-27777 | | References | http://www.sigmaaldrich.com/catalog/product/aldrich/213373?lang=en®ion=US
http://www.sigmaaldrich.com/catalog/product/sial/83275?lang=en®ion=US
Yamanaka M et al. "Origin of High E -Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α′-Alkenediol: A Computational and Experimental Study." Journal of Organic Chemistry 80.6(2015):3075-82.
J. G. Ma?ecki, and A. Maroń. "Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand."Transition Metal Chemistry 38.2(2013):133-142. |
| | 4-Pyrrolidinopyridine Preparation Products And Raw materials |
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