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| | 2-METHYL-4-PHENYL-2-BUTANOL Basic information |
| | 2-METHYL-4-PHENYL-2-BUTANOL Chemical Properties |
| Melting point | 31-33 °C(lit.) | | Boiling point | 144 °C85 mm Hg(lit.) | | density | 0.966 g/mL at 25 °C(lit.) | | vapor pressure | 4.1hPa at 20℃ | | FEMA | 3629 | 2-METHYL-4-PHENYL-2-BUTANOL | | refractive index | n20/D 1.509(lit.) | | Fp | >230 °F | | pka | 15.17±0.29(Predicted) | | form | powder to lump to clear liquid | | Specific Gravity | 0.966 | | color | White or Colorless to Light yellow | | Odor | at 100.00 %. clean fresh green rose linalool lily violet | | Odor Type | floral | | Water Solubility | 4.569g/L at 20℃ | | JECFA Number | 1477 | | LogP | 2.41 at 25℃ | | CAS DataBase Reference | 103-05-9(CAS DataBase Reference) | | EPA Substance Registry System | .alpha.,.alpha.-Dimethylbenzenepropanol (103-05-9) |
| Hazard Codes | Xi | | Risk Statements | 41 | | Safety Statements | 26-36/37/39 | | WGK Germany | 2 | | RTECS | EL5785000 | | HS Code | 29062990 | | Toxicity | LD50 orl-rat: 2200 mg/kg FCTXAV 12,517,74 |
| | 2-METHYL-4-PHENYL-2-BUTANOL Usage And Synthesis |
| Description | 2-Methyl-4-phenyl-2-butanol has a floral green, fruity, linalool
character with a mildly herbaceous odor. May be prepared by
reaction of phenylethyl magnesium chloride with acetone. | | Chemical Properties | 2-METHYL-4-PHENYL-2-BUTANOL is a colorless
liquid with a dry, floral, lily-like odor. It has been identified in cocoa aroma
and is prepared by a Grignard reaction of benzylacetone and methyl magnesium
chloride. It is used in blossom compositions. | | Chemical Properties | Colorless or light yellow liquid | | Chemical Properties | 2-Methyl-4-phenyl-2-butanol has a floral, green, fruity, linalool character and mildly herbaceous odor. | | Occurrence | Has apparently not been reported to occur in nature. | | Uses | 2-Phenethyl-2-propanol is a useful reagent in preparation of phenyldimethylsilyl group as a masked hydroxy group. | | Preparation | By reaction of phenylethyl magnesium chloride with acetone | | Aroma threshold values | Aroma characteristics at 1.0%: clean, fresh, floral reminiscent of rose and violet | | Taste threshold values | Taste characteristics at 10–40 ppm: floral, rosy, oily with a slight fruity nuance | | Synthesis Reference(s) | The Journal of Organic Chemistry, 60, p. 4922, 1995 DOI: 10.1021/jo00120a042 | | Safety Profile | Moderately toxic by ingestion andskin contact. When heated to decomposition it emits acridsmoke and irritating fumes. |
| | 2-METHYL-4-PHENYL-2-BUTANOL Preparation Products And Raw materials |
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