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| | PHENYLBORON DICHLORIDE Basic information |
| | PHENYLBORON DICHLORIDE Chemical Properties |
| Melting point | 7 °C | | Boiling point | 66 °C11 mm Hg(lit.) | | density | 1.224 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.545(lit.) | | Fp | −5 °F | | storage temp. | 2-8°C | | form | Liquid | | color | Colorless | | Specific Gravity | 1.224 | | Water Solubility | Soluble in water (Reacts violently). | | Sensitive | Moisture Sensitive | | BRN | 2243576 | | CAS DataBase Reference | 873-51-8(CAS DataBase Reference) |
| | PHENYLBORON DICHLORIDE Usage And Synthesis |
| Chemical Properties | clear colorless liquid | | Uses | Catalyst for:
- Antiproliferative macrolide and cell migration inhibitor lactimidomycin
- Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
- Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
- Stereoselective alkylative ring opening of cyclic anhydrides
- Cross-metathesis reaction of amino derivatives with olefins
- Asymmetric acetate aldol reactions
- The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
| | Uses | Dichlorophenylborane is widely used as a catalyst in Antiproliferative macrolide and cell migration inhibitor lactimidomycin and in enantioselective synthesis of polypeptide segments using vinylogous Mukaiyama aldol reactions and in enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives. It is a stereo selective alkylative ring opening of cyclic anhydrides and in cross-metathesis reaction of amino derivatives with olefines. |
| | PHENYLBORON DICHLORIDE Preparation Products And Raw materials |
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