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ChemicalBook >> CAS DataBase List >> [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride price.
  • $5 - $512.51
  • Product name: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
  • CAS: 15629-92-2
  • MF: C27H26Cl2NiP2
  • MW: 542.04
  • EINECS:605-052-3
  • MDL Number:MFCD00015318
  • Synonyms:NiCl2(DPPP)NiCl2(DPPP);1.3-Bis(dipheny phosphine) propane nickel(II)chloride;DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE;NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE;1,3-Bis-(diphenylphosphino)-propane nickel chloride;Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%;(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride;Dichloro1,3-Bis-(diphenylphosphino ) propane nickel (II)(DPPE.Nicl2) 98%
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  • Alfa Aesar
  • Alichem
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  • ManufacturerAlfa Aesar
  • Product number030167
  • Product descriptionDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
  • Packaging2g
  • Price$60.7
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number030167
  • Product descriptionDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
  • Packaging10g
  • Price$188
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number15629922
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride
  • Packaging500g
  • Price$291
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number15629922
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride
  • Packaging1000g
  • Price$475.2
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging10g
  • Price$8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging25g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging100g
  • Price$49
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging500g
  • Price$218
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA133473
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging1kg
  • Price$415
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006656
  • Product description1,3-BIS(DIPHENYLPHOSPHINO)PROPANENICKEL(II)CHLORIDE 95.00%
  • Packaging5G
  • Price$412.9
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0006656
  • Product description1,3-BIS(DIPHENYLPHOSPHINO)PROPANENICKEL(II)CHLORIDE 95.00%
  • Packaging25G
  • Price$433
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR70169
  • Product description[1,3-Bis(diphenylphosphino)propane]nickel(II)chloride
  • Packaging25g
  • Price$102
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR70169
  • Product description[1,3-Bis(diphenylphosphino)propane]nickel(II)chloride
  • Packaging100g
  • Price$186
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS445741
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS445741
  • Product description1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98%
  • Packaging10g
  • Price$8
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 030167 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) 2g $60.7 2024-03-01 Buy
Alfa Aesar 030167 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) 10g $188 2024-03-01 Buy
Alichem 15629922 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 500g $291 2021-12-16 Buy
Alichem 15629922 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 1000g $475.2 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 5g $6 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 10g $8 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 25g $14 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 100g $49 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 500g $218 2021-12-16 Buy
Ambeed A133473 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 1kg $415 2021-12-16 Buy
American Custom Chemicals Corporation ING0006656 1,3-BIS(DIPHENYLPHOSPHINO)PROPANENICKEL(II)CHLORIDE 95.00% 5G $412.9 2021-12-16 Buy
American Custom Chemicals Corporation ING0006656 1,3-BIS(DIPHENYLPHOSPHINO)PROPANENICKEL(II)CHLORIDE 95.00% 25G $433 2021-12-16 Buy
Apolloscientific OR70169 [1,3-Bis(diphenylphosphino)propane]nickel(II)chloride 25g $102 2021-12-16 Buy
Apolloscientific OR70169 [1,3-Bis(diphenylphosphino)propane]nickel(II)chloride 100g $186 2021-12-16 Buy
Arctom AS445741 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 5g $6 2021-12-16 Buy
Arctom AS445741 1,3-Bis(diphenylphosphino)propanenickel(II)chloride 98% 10g $8 2021-12-16 Buy

Properties

Melting point :213 °C (dec.)(lit.)
storage temp. :Inert atmosphere,Room Temperature
form :crystal
color :red
Water Solubility :insoluble
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIKey :ZBQUMMFUJLOTQC-UHFFFAOYSA-L
CAS DataBase Reference :15629-92-2(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger GHS hazard pictograms P261, P285, P304+P341, P342+P311,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
Precautionary statements:
P201 Obtain special instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

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