4,4'-Oxybis(benzoyl Chloride) synthesis
- Product Name:4,4'-Oxybis(benzoyl Chloride)
- CAS Number:7158-32-9
- Molecular formula:C14H8Cl2O3
- Molecular Weight:295.12
2215-89-6
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$6.00/10g
7158-32-9
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$9.00/250mg
Yield:7158-32-9 95%
Reaction Conditions:
with thionyl chloride in N,N-dimethyl-formamide;toluene at 95; for 3 h;
Steps:
Synthesis of Acid Chloride Product (A)
4,4'-diphenyl ether dicarboxylic acid 25.3 g (0.096 mol), 0.85 g (0.012 mol) of dimethylformamide and 80 ml of toluene was prepared. For the first mixed solution in the stirring state, 58.4 g (0.46 mol) of thionyl chloride, And 20 ml of toluene Was gradually added dropwise at room temperature. After completion of the dropwise addition, the liquid obtained was heated to 95 ° C., It was refluxed for 3 h. Then, by allowing the yellow transparent liquid obtained after heating / refluxing to cool, It has the following molecular structure 4,4'-diphenyl ether dicarboxylic acid chloride (Hereinafter referred to as "acid chloride (A)" In some cases) as a toluene solution. further, The toluene solution was applied to a rotary evaporator, and toluene, Thionyl chloride and hydrogen chloride were removed, 4,4'- Diphenyl ether dicarboxylic acid chloride solid 26.9 g (0.091 mol, 95% yield) Was obtained.
References:
TOKUYAMA DENTAL CORPORATION;TAKAHASHI, AYUMU JP2017/149660, 2017, A Location in patent:Paragraph 0232; 0233
2215-76-1
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$60.00/100mg
7158-32-9
157 suppliers
$9.00/250mg
6508-04-9
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$46.00/250 mg
7158-32-9
157 suppliers
$9.00/250mg