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1159-54-2

1159-54-2 Structure

1159-54-2 Structure
IdentificationMore
[Name]

TRIS(4-CHLOROPHENYL)PHOSPHINE
[CAS]

1159-54-2
[Synonyms]

TRI(4-CHLOROPHENYL)PHOSPHINE
TRI(P-CHLOROPHENYL)PHOSPHINE
TRIS(4-CHLOROPHENYL)PHOSPHINE
TRIS(P-CHLOROPHENYL)PHOSPHINE
Phosphine, tris(4-chlorophenyl)-
Phosphine, tris(p-chlorophenyl)-
Tri(p-chlorophenyl)phosphine,99%
[EINECS(EC#)]

214-596-7
[Molecular Formula]

C18H12Cl3P
[MDL Number]

MFCD00013639
[Molecular Weight]

365.62
[MOL File]

1159-54-2.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

100-103 °C (lit.)
[Boiling point ]

427.6±40.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

white
[Sensitive ]

Air Sensitive
[BRN ]

751458
[CAS DataBase Reference]

1159-54-2(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

3278
[WGK Germany ]

3
[TSCA ]

No
[PackingGroup ]

III
[HS Code ]

29310099
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Catalyst for:
  • Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
  • Solvent-free Heck reactions

Cocatalyst in:
  • Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
  • Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
  • Rhodium-catalyzed hydrogenation reactions
  • Platinum-catalyzed allylation reactions
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
Spectrum DetailBack Directory
[Spectrum Detail]

TRIS(4-CHLOROPHENYL)PHOSPHINE(1159-54-2)1HNMR
TRIS(4-CHLOROPHENYL)PHOSPHINE(1159-54-2)31PNMR
TRIS(4-CHLOROPHENYL)PHOSPHINE(1159-54-2)IR
TRIS(4-CHLOROPHENYL)PHOSPHINE(1159-54-2)Raman
TRIS(4-CHLOROPHENYL)PHOSPHINE(1159-54-2)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tris(4-chlorophenyl)phosphine, 97%(1159-54-2)
[Alfa Aesar]

Tris(4-chlorophenyl)phosphine, 98%(1159-54-2)
[Sigma Aldrich]

1159-54-2(sigmaaldrich)
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