| Identification | Back Directory | [Name]
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE | [CAS]
118949-61-4 | [Synonyms]
2,6-Bis((S)
-4-isopropyl-4,5-dihydrooxazol-2-yl)
2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE
(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE
2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.
2,6-Bis((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine
2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine 99%
(S, S) -2,6- bis (4-isopropyl-2-oxazoline-2-yl) pyridine
2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%
(S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
(-)-2,6-Bis[(4S)-4-(i-propyl)-2-oxazolin-2-yl]pyridine, 98+% (S)-(i-Pr)-pybox
(S,S)-2,2μ-(2,6-Pyridinediyl)bis(4-isopropyl-2-oxazoline), (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine | [Molecular Formula]
C17H23N3O2 | [MDL Number]
MFCD00191815 | [MOL File]
118949-61-4.mol | [Molecular Weight]
301.38 |
| Chemical Properties | Back Directory | [Melting point ]
155-157 °C(lit.)
| [alpha ]
-120° (c 1.0, CH2Cl2) | [Boiling point ]
457.1±30.0 °C(Predicted) | [density ]
1.23±0.1 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [form ]
crystal | [pka]
3.78±0.70(Predicted) | [color ]
white | [optical activity]
[α]25/D 118°, c = 0.7 in methylene chloride | [BRN ]
5824976 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder or crystal or chunks | [Uses]
Used as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation. |
| Questions And Answer | Back Directory | [Reaction]
- Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
- Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
- Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
- Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
- Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
- Ligand for osmium catalyzed enantioselective transfer hydrogenation.
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