| Identification | Back Directory | [Name]
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& | [CAS]
357209-32-6 | [Synonyms]
(R,S)-In-Pybox
(3aR,8aS)-in-pybox
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
2,6-bis((3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)pyridine
2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine,95%,99%ee
(+)-2,6-Bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-
(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.
(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 98% (99% ee)
(3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
(3aS,8bR)-2-[6-[(3aS,8bR)-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridin-2-yl]-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazole | [Molecular Formula]
C25H19N3O2 | [MDL Number]
MFCD09265074 | [MOL File]
357209-32-6.mol | [Molecular Weight]
393.44 |
| Chemical Properties | Back Directory | [Melting point ]
284 °C (dec.) | [Boiling point ]
633.0±55.0 °C(Predicted) | [density ]
1.50±0.1 g/cm3(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [pka]
4.35±0.20(Predicted) | [optical activity]
[α]20/D +386°, c = 1 in methylene chloride(lit.) |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
Catalytic ligand used for:
- [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
- Enantioselective Mukaiyama-aldol reactions
- Enantioselective carbonyl-ene reactions
- Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
- Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
- Enantioselective Diels-Alder reaction
- Ni-catalyzed cross-coupling reactions
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