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119-51-7

119-51-7 Structure

119-51-7 Structure
IdentificationMore
[Name]

1-Phenyl-1,2-propanedione-2-oxime
[CAS]

119-51-7
[Synonyms]

1-PHENYL-1,2-PROPANEDIONE-2-OXIME
2-HYDROXYIMINOPROPIOPHENONE
2-ISONITROSOPROPIOPHENONE
2-PHENYL-1,2-PROPANEDIONE-2-OXIME
ALPHA-ISONITROSOPROPIOPHENONE
A-OXIMINOPROPIOPHENONE
ISONITROSO PROPIOPHENONE
TIMTEC-BB SBB003926
(2E)-1-Phenyl-1,2-propanedione 2-oxime
1,2-Propanedione, 1-phenyl-, 2-oxime
2-propanedione,1-phenyl-2-oxime
alpha-Oximinopropiophenone
isonitroso-propiophenon
Propiophenone, isonitroso-
ra58
Oximinopropiophenone
A-ISONITROSOPROPIOPHENONE
1-PHENYL-1,2-PROPANEDIONE 2-OXIME 99%
2-Hydroxyimino-1-phenylpropan-1-one
1-Phenyl-2-(hydroxyimino)-1-propanone
[EINECS(EC#)]

204-329-2
[Molecular Formula]

C9H9NO2
[MDL Number]

MFCD00002115
[Molecular Weight]

163.17
[MOL File]

119-51-7.mol
Chemical PropertiesBack Directory
[Appearance]

WHITE TO LIGHT YELLOW CRYSTALS
[Melting point ]

113-115 °C(lit.)
[Boiling point ]

290.25°C (rough estimate)
[density ]

1.2021 (rough estimate)
[refractive index ]

1.5460 (estimate)
[storage temp. ]

2-8°C
[solubility ]

soluble in Methanol
[form ]

Crystals
[pka]

9.28±0.10(Predicted)
[color ]

White to light yellow
[λmax]

398nm(MeOH)(lit.)
[CAS DataBase Reference]

119-51-7(CAS DataBase Reference)
[NIST Chemistry Reference]

1-Phenyl-1,2-propane-dione-2-oxime(119-51-7)
[EPA Substance Registry System]

119-51-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

2
[RTECS ]

UH2975000
[HS Code ]

29280090
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Phenyl-1,2-propanedione-2-oxime(119-51-7).msds
Hazard InformationBack Directory
[Chemical Properties]

WHITE TO LIGHT YELLOW CRYSTALS
[Uses]

Reactant involved in synthesis of:
  • Cyclometalated iridium complexes for photophysical and electrochemical studies
  • Hydroimidazothiazoles via iodination and cyclization reactions

Reactant involved in:
  • Sonogashira coupling reactions
  • Allylation of aromatic aldehydes using imidazole oside catalysts
  • Beckmann rearrangement of α-oximinoketones

Reagent used in the colorimetric determination of urea
[Synthesis Reference(s)]

Organic Syntheses, Coll. Vol. 2, p. 363, 1943
Tetrahedron Letters, 30, p. 2833, 1989 DOI: 10.1016/S0040-4039(00)99137-8
Spectrum DetailBack Directory
[Spectrum Detail]

1-Phenyl-1,2-propanedione-2-oxime(119-51-7)MS
1-Phenyl-1,2-propanedione-2-oxime(119-51-7)1HNMR
1-Phenyl-1,2-propanedione-2-oxime(119-51-7)13CNMR
1-Phenyl-1,2-propanedione-2-oxime(119-51-7)IR1
1-Phenyl-1,2-propanedione-2-oxime(119-51-7)IR2
1-Phenyl-1,2-propanedione-2-oxime(119-51-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Phenyl-1,2-propanedione-2-oxime, 99%(119-51-7)
[Sigma Aldrich]

119-51-7(sigmaaldrich)
[TCI AMERICA]

2-Isonitrosopropiophenone,>98.0%(GC)(119-51-7)
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