| Identification | More | [Name]
NITRONIUM TETRAFLUOROBORATE | [CAS]
13826-86-3 | [Synonyms]
NITRONIUM TETRAFLUOROBORATE
NITRYL TETRAFLUOROBORATE
nitronium,tetrafluoroborate(1-)
nitrylfluoborate
tetrafluoro-borate(1-nitryl
Nitronium tetrafluorborate
NITRONIUM TETRAFLUOROBORATE, 95+%
NITRONIUM TETRAFLUOROBORATE, 0.5M SOLUTI ON IN SULFOLANE
NITRONIUM TETRAFLUOROBORATE SOLUTION, ~0 .5 M IN SULFOLANE
Nitroniumtetrafluoroborate,min.97%
Borate(1-), tetrafluoro-, nitryl
nitronium tetrafluoroborate solution
Nitronium tetrafluoroborate 95%
Nitronium tetrafluoroborate,97%
Nitronium tetrafluoroborate, min. 97% | [EINECS(EC#)]
237-533-5 | [Molecular Formula]
BF4NO2 | [MDL Number]
MFCD00011432 | [Molecular Weight]
132.81 | [MOL File]
13826-86-3.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless crystalline solid | [Melting point ]
200 °C | [density ]
1.29 g/mL at 20 °C
| [storage temp. ]
2-8°C
| [solubility ]
Acetonitrile (Slightly, Heated) | [form ]
crystal | [color ]
white | [Stability:]
Stable, but may decompose in water on exposure to moist air. Incompatible with water, strong oxidizing agents. | [Water Solubility ]
Decomposes in water. | [Decomposition ]
decomposes to NO2F and BF3 at temperatures >180 °C. | [Sensitive ]
Hygroscopic | [CAS DataBase Reference]
13826-86-3(CAS DataBase Reference) | [EPA Substance Registry System]
Borate(1-), tetrafluoro-, nitryl (13826-86-3) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3264 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
QX8620000
| [F ]
10-21 | [Hazard Note ]
Corrosive/Hygroscopic | [TSCA ]
T | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28429090 | [Toxicity]
mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#05621, |
| Hazard Information | Back Directory | [Chemical Properties]
colourless crystalline solid | [Uses]
Nitronium Tetrafluoroborate is used in the preparation of triazolyl glycoside as galectin-3 inhibitors. | [General Description]
Nitronium Tetrafluoroborate is used as a electrophilic nitrating agent; mild oxidant; hydride and halide abstracting agent. | [Solubility in organics]
Nitronium Tetrafluoroborate is soluble in sulfolane, acetonitrile; slightly soluble in nitromethane. Compared with NO2
+BF4
-,
NO2
+PF6
- has much higher solubility in organic solvents. | [storage]
Due to its hygroscopic nature, Nitronium Tetrafluoroborate (NO2 +BF4 -) should be stored
and used under anhydrous conditions. Commercial NO2
+BF4
- often contains varying amounts of
NO+BF4
-. Removal of the NO+ from NO2
+BF4
- is difficult. Therefore, pure nitronium
tetrafluoroborate should be prepared directly from urea-treated purified HNO3. |
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