ChemicalBook--->CAS DataBase List--->14324-55-1

14324-55-1

14324-55-1 Structure

14324-55-1 Structure
IdentificationMore
[Name]

Ethyl ziram
[CAS]

14324-55-1
[Synonyms]

DIETHYLDITHIOCARBAMIC ACID ZINC SALT
ETHYL ZIMATE
ZDEC
ZINC DIETHYLDITHIOCARBAMATE
ZINC N,N-DIETHYLDITHIOCARBAMATE
Accelerator EZ powder
AcceleratorZDC
Ancazate ET
Bis(diethylcarbamodithioato-S,S') zinc
bis(diethylcarbamodithioato-S,S’)-,(T-4)-Zinc
bis(diethyldithiocarbamate)zinc
bis(diethyldithio-carbamate)zinc
bis(diethyldithiocarbamato)-zin
Bis(diethyldithiocarbamato)zinc
bis(diethyldithiocarbamato)zinc[qr]
Carbamodithioic acid, diethyl-, zinc salt
diethyl-carbamodithioicacizincsalt
Etazin
Ethasan
Ethazate
[EINECS(EC#)]

238-270-9
[Molecular Formula]

C10H20N2S4Zn
[MDL Number]

MFCD00064798
[Molecular Weight]

361.93
[MOL File]

14324-55-1.mol
Chemical PropertiesBack Directory
[Melting point ]

178-181 °C(lit.)
[Boiling point ]

330.6°C (estimate)
[density ]

1,48 g/cm3
[vapor pressure ]

0.007Pa at 25℃
[Fp ]

204°(400°F)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

DMSO (Sparingly), Methanol (Slightly, Heated, Sonicated)
[form ]

solid
[color ]

White
[Specific Gravity]

1.48
[Water Solubility ]

Insoluble in water. Soluble in benzene carbon disulfide and organic liquids.
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[InChI]

1S/2C5H11NS2.Zn/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2
[Contact allergens]

Diethyldithiocarbamate zinc is a rubber component used as a vulcanization accelerator. Oxidation of this carbamate leads to tetraethylthiuram disulfide. It can be responsible for rubber dermatitis in health personnel. It was contained in “carba-mix.”
[InChIKey]

RKQOSDAEEGPRER-UHFFFAOYSA-L
[SMILES]

CCN(CC)C(=S)S[Zn]SC(=S)N(CC)CC
[LogP]

3.11
[Uses]

Rubber vulcanization accelerator, especially for latex foam; heat stabilizer for polyethylene.
[CAS DataBase Reference]

14324-55-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Bis(diethyldithiocarbamate)zinc complex(14324-55-1)
[EPA Substance Registry System]

14324-55-1(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Definition]

ChEBI: Zinc diethyldithiocarbamate is a dithiocarbamate salt that is the zinc salt of diethyldithiocarbamic acid. It is an accelerator and activator for natural rubber. It has a role as an antifungal agrochemical. It is a dithiocarbamate salt and a zinc molecular entity. It contains a diethyldithiocarbamate and a zinc(2+). It is functionally related to a diethyldithiocarbamic acid.
[Hazard]

Strong irritant to eyes and mucous membranes.
[Flammability and Explosibility]

Notclassified
[reaction suitability]

core: zinc
reagent type: catalyst
[Safety Profile]

Poison by intraperitoneal route.Moderately toxic by ingestion and subcutaneous routes.Severe irritant to eyes, nose, and throat. Questionablecarcinogen with experimental carcinogenic andtumorigenic data. Mutation data reported. When heated todecompos
[Purification Methods]

Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It also crystallises from xylene, m 180o. [Beilstein 4 II 613.] TOXIC.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS07,GHS08,GHS09
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H317-H319-H335-H373-H410
[Precautionary statements ]

P273-P280-P301+P312-P302+P352-P305+P351+P338-P314
[Hazard Codes ]

Xn,N
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S24:Avoid contact with skin .
S37:Wear suitable gloves .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

ZH0350000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29302000
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT RE 2 Oral
STOT SE 3
[Hazardous Substances Data]

14324-55-1(Hazardous Substances Data)
[Toxicity]

LD50 orl-rat: 3340 mg/kg 28ZPAK -,11,72
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethylamine-->Zinc sulphate-->Sodium formate-->Diethyl disulfide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Zinc bis(diethyldithiocarbamate)(14324-55-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl ziram(14324-55-1)MS
Ethyl ziram(14324-55-1)1HNMR
Ethyl ziram(14324-55-1)IR1
Ethyl ziram(14324-55-1)IR2
Ethyl ziram(14324-55-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Zinc diethyldithiocarbamate, Zn 17-19.5%(14324-55-1)
[Sigma Aldrich]

14324-55-1(sigmaaldrich)
[TCI AMERICA]

Zinc Diethyldithiocarbamate,>99.0%(T)(14324-55-1)
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