16854-32-3

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16854-32-3 Structure

Identification	More
[Name] (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
[CAS] 16854-32-3
[Synonyms] (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL (1S,2S)-(+)-THIOMICAMINE L-THIOMICAMINE 2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol [S(R,R)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol thiomicamine (1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol (1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
[EINECS(EC#)] 240-878-4
[Molecular Formula] C10H15NO2S
[MDL Number] MFCD00134212
[Molecular Weight] 213.3
[MOL File] 16854-32-3.mol

Chemical Properties	Back Directory
[Melting point ] 151-154 °C(lit.)
[Boiling point ] 428.2±45.0 °C(Predicted)
[density ] 1.25±0.1 g/cm3(Predicted)
[pka] 11.75±0.45(Predicted)
[optical activity] [α]25/D +25°, c = 1 in ethanol
[CAS DataBase Reference] 16854-32-3(CAS DataBase Reference)

Safety Data	Back Directory
[Hazard Codes ] Xi
[Risk Statements ] R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ] S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ] 3

[Uses]

(1S,2S)-(+)-Thiomicamine can be used:

As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.
As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.
As a chiral base in the resolution of an angiotensin II type 2 receptor [AT₂R] antagonist named EMA401.

Spectrum Detail	Back Directory
[Spectrum Detail] (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(16854-32-3)¹HNMR (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(16854-32-3)IR (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(16854-32-3)Raman

Well-known Reagent Company Product Information	Back Directory
[Sigma Aldrich] 16854-32-3(sigmaaldrich)

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