| Identification | More | [Name]
Paraquat dichloride | [CAS]
1910-42-5 | [Synonyms]
1,1'-DIMETHYL-4,4'-BIPYRIDINIUM
1,1'-Dimethyl-4,4'-bipyridinium cation
1,1'-DIMETHYL-4,4'-BIPYRIDINIUM DICHLORIDE
1,1'-DIMETHYL-4,4'-BIPYRIDINIUM DICHLORIDE TRIHYDRATE
1,1'-Dimethyl-4,4'-bipyridinium dimethosulfate
1,1'-dimethyl-4,4'-bipyridinium ion
ARIAL GRAMOXONE(R)
DEXTRONE X(R)
Dimethyl-4,4'-bipyridinium bis(methyl sulfate)
DIMETHYLDIPYRIDYL CHLORIDE
EFOXON
grammoxone
GRAMOXONE
GRAMOXONE(R)
HERBAXON
'LGC' (1622)
METHYL VIOLOGEN
METHYL VIOLOGEN DICHLORIDE
METHYL VIOLOGEN N-HYDRATE
n,n'-dimethyl-4,4'-bipyridinium dichloride | [EINECS(EC#)]
217-615-7 | [Molecular Formula]
C12H14Cl2N2 | [MDL Number]
MFCD00011986 | [Molecular Weight]
257.16 | [MOL File]
1910-42-5.mol |
| Chemical Properties | Back Directory | [Description]
Paraquat dichloride is a dark blue liquid, non-combustible, stable herbicide chemical. It is
incompatible with strong oxidising agents. On contact with fire paraquat decomposes gives
off irritating or toxic fumes (or gases), nitrogen oxides, and hydrogen chloride. Paraquat
dichloride contact and storage destroys metal. Paraquat dichloride hydrolyses in alkaline
media and reacts with aluminium to produce hydrogen gas.
Paraquat (N,N′-dimethyl-4,4′-bipyridinium dichloride) is one of the most widely used herbicides
in the world. Paraquat dichloride is a herbicide currently registered to control weeds
and grasses in many agricultural and non-agricultural areas. It is used preplant or preemergence
on vegetables, grains, cotton, grasses, sugar cane, peanuts, potatoes, and tree plantation
areas; post-emergence around fruit crops, vegetables, trees, vines, grains, soybeans,
and sugar cane. It is also used on non-crop areas such as public airports, electric transformer
stations, and around commercial buildings to control weeds. It has been reported that about
seven pesticide products are registered which contain the active ingredient paraquat dichloride
and classified as restricted use pesticides (RUPs). Paraquat dichloride and the products
are primarily intended for ‘Occupational Use’. In the United States, Paraquat is classified as
‘restricted commercial use’, and people must obtain a license to use the product. | [Appearance]
Paraquat is a yellow solid with a faint,
ammonia-like odor. | [Melting point ]
>300 °C(lit.)
| [Boiling point ]
403.89°C (rough estimate) | [density ]
1.25 | [vapor pressure ]
0Pa at 25℃ | [refractive index ]
1.6400 (estimate) | [storage temp. ]
0-6°C | [solubility ]
Methanol (Sligthly) | [form ]
Crystals or Crystalline Powder | [color ]
Beige or pink to brown | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
soluble | [Merck ]
7031 | [Contact allergens]
Paraquat is a quaternary ammonium compound with herbicide
properties, as diquat. It is contained in Cekuquat® or
Dipril®. It can cause contact and phototoxic contact dermatitis,
acne, and leukoderma mainly in agricultural workers. | [LogP]
-4.5 at 20℃ | [CAS DataBase Reference]
1910-42-5(CAS DataBase Reference) | [EPA Substance Registry System]
1910-42-5(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
off-white powder | [General Description]
Colorless to yellow crystalline solid. Used as a contact herbicide and desiccant. | [Reactivity Profile]
PARAQUAT DICHLORIDE(1910-42-5) is stable in acidic media, but unstable in alkaline media. PARAQUAT DICHLORIDE(1910-42-5) is photochemically decomposed by UV irradiation in aqueous solutions and is rapidly inactivated by soil. The neat chemical may be sensitive to light. This compound is corrosive to metal and PARAQUAT DICHLORIDE(1910-42-5) can react with strong acids, bases, and oxidizing agents. PARAQUAT DICHLORIDE(1910-42-5) is hydrolyzed by alkali compounds and PARAQUAT DICHLORIDE(1910-42-5) is inactivated by inert clays and anionic surfactants. | [Air & Water Reactions]
Water soluble. | [Health Hazard]
Can cause death due to severe injury to the lungs. The lowest lethal oral dose reported in humans is 43 mg/kg. | [Potential Exposure]
Those engaged in manufacture,
formulation and application of this herbicide. Classified
for restricted use: limited to use by a certified applicator, or
those under applicator’s direct supervision. | [Fire Hazard]
Avoid strong oxidizers. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including
resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical
attention. Give large quantities of water, or bentonite
clay in water, or activated charcoal in water; and induce
vomiting. Do not make an unconscious person vomit.
Medical observation is recommended for 2448 hours after
breathing overexposure, as pulmonary edema may be
delayed. As first aid for pulmonary edema, a doctor or
authorized paramedic may consider administering a drug or
other inhalation therapy. Obtain authorization and/or further
instructions from the local hospital for performance of
other invasive procedures. Rush to a health care facility. | [Shipping]
UN2781 Bipyridilium pesticide, solid, toxic,
Hazard Class: 6.1; Labels: 6.1-Poisonous materials. | [Incompatibilities]
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides (hydrolysis), alkylarylsulfonate
wetting agents. Corrosive to metals. Decomposes
in presence of ultraviolet (UV) light. Decomposes in heat
(see physical properties, above) and in the presence of UV
light, producing nitrogen oxides, hydrogen chloride. | [Waste Disposal]
Paraquat is rapidly inactivated
in soil. It is also inactivated by anionic surfactants.
Therefore an effective and environmentally safe disposal
method would be to mix the product with ordinary household
detergent and bury the mixture in clay soil. In
accordance with 40CFR165, follow recommendations for
the disposal of pesticides and pesticide containers. Must be
disposed properly by following package label directions or
by contacting your local or federal environmental control
agency, or by contacting your regional EPA office. Consult
with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing
this contaminant (≥100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment,
and waste disposal. | [Definition]
ChEBI:Paraquat dichloride is an organic chloride salt. It has a role as a herbicide and a photosystem-I inhibitor. It contains a paraquat. | [Flammability and Explosibility]
Notclassified | [Safety Profile]
A human poison by ingestion. Poison experimentally by ingestion, skin contact, intraperitoneal, intravenous, and subcutaneous routes. Human systemic effects by ingestion: acute renal failure, acute tubular necrosis, cough, diarrhea, dyspnea, headache, hyp | [Purification Methods]
Recrystallise the dichloride from MeOH/acetone mixture. It has also been recrystallised three times from absolute EtOH [Bancroft et al. Anal Chem 53 1390 1981]. Dry it at 80o in a vacuum. [Beilstein 23/8 V 30.] |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
R24/25:Toxic in contact with skin and if swallowed .
R26:Very Toxic by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
R48/25:Toxic: danger of serious damage to health by prolonged exposure if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S22:Do not breathe dust .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [OEB]
D | [OEL]
TWA: 0.1 mg/m3 (resp) [skin] | [RIDADR ]
UN 2811 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
DW2275000
| [HazardClass ]
6.1(a) | [PackingGroup ]
II | [HS Code ]
29333990 | [Toxicity]
LD50 orally in rats: 125 mg/kg (Conning) | [IDLA]
1 mg/m3 |
|