| Identification | More | [Name]
6-Chlorohexanol | [CAS]
2009-83-8 | [Synonyms]
1-CHLORO-6-HYDROXYHEXANE
6-CHLORO-1-HEXANOL
6-Chlorohexanol
HEXAMETHYLENE CHLOROHYDRIN
1-Chloro-6-hexanol
6-chloro-1-hexano
omega-chlorohexanol
Chlorohexanol
6-chlorohexan-1-ol
6-Chlor-1-Hexanol
1-CHLORO-6-HYDROXYHEXANE, 6-CHLORO-1-HEXANOL
6-CHLOROHEXYL CYANIDE 97%
1-Chloro-6-hydroxyhexane, Hexamethylene chlorohydrin
6-Chloro-1-hexanol ,95%
6-Chlorohexyl alcohol | [EINECS(EC#)]
217-925-2 | [Molecular Formula]
C6H13ClO | [MDL Number]
MFCD00002984 | [Molecular Weight]
136.62 | [MOL File]
2009-83-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to pale yellow liquid | [Melting point ]
102 °C | [Boiling point ]
108-112 °C14 mm Hg(lit.)
| [density ]
1.024 g/mL at 25 °C(lit.)
| [vapor pressure ]
1.066hPa at 21.1℃ | [refractive index ]
n20/D 1.456(lit.)
| [Fp ]
210 °F
| [storage temp. ]
Refrigerator | [solubility ]
Soluble in dimethylformamide. | [form ]
Liquid | [pka]
15.17±0.10(Predicted) | [color ]
Clear colorless to pale yellow | [Specific Gravity]
1.024 | [Water Solubility ]
11.3g/L at 20℃ | [Detection Methods]
GC | [BRN ]
1697307 | [InChIKey]
JNTPTNNCGDAGEJ-UHFFFAOYSA-N | [LogP]
1.86 at 30℃ | [CAS DataBase Reference]
2009-83-8(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Hexanol, 6-chloro-(2009-83-8) | [EPA Substance Registry System]
2009-83-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R20/21:Harmful by inhalation and in contact with skin .
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
2810 | [WGK Germany ]
3
| [RTECS ]
MO9160000
| [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29055900 | [Toxicity]
mouse,LD50,intraperitoneal,> 100mg/kg (100mg/kg),Journal of Organic Chemistry. Vol. 21, Pg. 739, 1956. |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to pale yellow liquid | [Uses]
6-Chloro-1-hexanol is used in the preparation of its corresponding bromide by reaction with sodium bromide using N,N-dimethylformamide and dibromomethane (2:1) as a solvent. It is utilized in the selective elimination of 6-chloro-1-hexene from esters of 6-chloro-1-hexanol. | [Preparation]
6-Chlorohexanol is obtained from the reaction of 1,6-Hexanediol with hydrochloric acid. | [Synthesis Reference(s)]
Organic Syntheses, Coll. Vol. 3, p. 446, 1955
Tetrahedron Letters, 36, p. 3161, 1995 DOI: 10.1016/0040-4039(95)00501-3 |
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