Identification | More | [Name]
3-(Trifluoromethoxy)bromobenzene | [CAS]
2252-44-0 | [Synonyms]
1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE 3-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE 3-BROMO(TRIFLUOROMETHOXY)BENZENE 3-(TRIFLUOROMETHOXY)BROMOBENZENE BUTTPARK 91\57-27 M-BROMO(TRIFLUOROMETHOXY)BENZENE Anisole, m-bromo-alphaalphaalpha-trifluoro- 3-Bromo-1-(trifluoromethoxy)benzene 3-(Trifluoromethoxy)bromobenzene 99% 3-(Trifluoromethoxy)bromobenzene99% 1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE/3-BROMO-TRIFLUOROMETHOXYBENZENE 1-BROMO-3-(TRIFLUOROMETHOXY)BENZENE 99% 1-Bromo-3-(trifluoromethoxy)benzene, 98+% | [Molecular Formula]
C7H4BrF3O | [MDL Number]
MFCD00040943 | [Molecular Weight]
241.01 | [MOL File]
2252-44-0.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
29049090 |
Hazard Information | Back Directory | [Chemical Properties]
Clear very faintly yellow liquid | [Uses]
1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl]. | [General Description]
1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes. |
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