| Identification | More | [Name]
4-Pyrrolidinopyridine | [CAS]
2456-81-7 | [Synonyms]
1-(4-PYRIDYL)PYRROLIDINE
4-(1-PYRROLIDINO)PYRIDINE
4-(1-PYRROLIDINYL)PYRIDINE
4-PYRROLIDIN-1-YL-PYRIDINE
4-PYRROLIDINOPYRIDINE
N-(4-PYRIDYL)PYRROLIDINE
TIMTEC-BB SBB004083
4-(1-Pyrrolidyl) pyridine
4-(1-Pyrrolidino)pyridine,98%
Pyridine, 4-(1-pyrrolidinyl)-
4-PYRROLIDINOPYRIDINE 99% | [EINECS(EC#)]
219-534-2 | [Molecular Formula]
C9H12N2 | [MDL Number]
MFCD00006415 | [Molecular Weight]
148.2 | [MOL File]
2456-81-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light brown crystalline mass | [Melting point ]
54-58 °C(lit.)
| [Boiling point ]
171-173 °C (20.2527 mmHg)
| [density ]
1.0628 (rough estimate) | [refractive index ]
1.5378 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Store at RT. | [solubility ]
methanol: 0.1 g/mL, clear
| [form ]
Crystalline Mass, Crystals and/or Chunks | [pka]
9.58±0.10(Predicted) | [color ]
White to yellow to light brown | [PH]
10.5 (3g/l, H2O, 21℃) | [Water Solubility ]
3 g/L (21 ºC) | [BRN ]
472443 | [InChIKey]
RGUKYNXWOWSRET-UHFFFAOYSA-N | [CAS DataBase Reference]
2456-81-7(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Light sensitive;Store under inert gas |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R25:Toxic if swallowed.
R34:Causes burns.
R41:Risk of serious damage to eyes.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2923 8/PG 3
| [WGK Germany ]
3
| [F ]
8-10-23 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29333999 |
| Questions and Answers (Q&A) | Back Directory | [Description]
4-Pyrrolidinopyridine is the pyridine derivative. It can be used as catalyst employed in polymerization reactions or Hypernucleophilic acylation catalyst. For example, it can be used as the catalyst for the geometry-selective (E-selective) acylation of tetrasubstituted α, α'-alkenediols. It can also be used as the ligand in metal complexes such as the Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes.
| [References]
http://www.sigmaaldrich.com/catalog/product/aldrich/213373?lang=en®ion=US
http://www.sigmaaldrich.com/catalog/product/sial/83275?lang=en®ion=US
Yamanaka M et al. "Origin of High E -Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α′-Alkenediol: A Computational and Experimental Study." Journal of Organic Chemistry 80.6(2015):3075-82.
J. G. Ma?ecki, and A. Maroń. "Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand."Transition Metal Chemistry 38.2(2013):133-142.
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