| Identification | More | [Name]
METHYL 2-FLUOROBENZOATE | [CAS]
394-35-4 | [Synonyms]
2-FLUOROBENZOIC ACID METHYL ESTER
METHYL 2-FLUOROBENZOATE
METHYL O-FLUOROBENZOATE
RARECHEM AL BF 0016
2-fluoro-benzoicacimethylester
Benzoic acid, 2-fluoro-, methyl ester
Benzoic acid, o-fluoro-, methyl ester
o-Fluorobenzoic acid, methyl ester
Methyl2-fluorobenzoate,98%
Methyl 2-fluorobenzoate 98%
2-FLUOROBENZOIC ACID METHYL ESTER 98+% | [EINECS(EC#)]
206-894-0 | [Molecular Formula]
C8H7FO2 | [MDL Number]
MFCD00017913 | [Molecular Weight]
154.14 | [MOL File]
394-35-4.mol |
| Chemical Properties | Back Directory | [Melting point ]
93°C | [Boiling point ]
109-110 °C/35 mmHg (lit.) | [density ]
1.21 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.502(lit.)
| [Fp ]
201 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
1.210 | [BRN ]
1862493 | [InChI]
InChI=1S/C8H7FO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3 | [InChIKey]
QAFJIJWLEBLXHH-UHFFFAOYSA-N | [SMILES]
C(OC)(=O)C1=CC=CC=C1F | [CAS DataBase Reference]
394-35-4(CAS DataBase Reference) | [EPA Substance Registry System]
Benzoic acid, 2-fluoro-, methyl ester (394-35-4) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN3272 | [WGK Germany ]
3
| [Hazard Note ]
Toxic | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29163990 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
Methyl 2-fluorobenzoate may be used to synthesize 2-fluoro-α-methylstyrene and 2-fluorophenyldiphenylmethanol. | [Synthesis Reference(s)]
Synthetic Communications, 21, p. 2377, 1991 DOI: 10.1080/00397919108021598 | [General Description]
Methyl 2-fluorobenzoate is an ortho-halogen-substituted methyl benzoate ester. It reacts with hydrazide to afford 2-fluorobenzoic hydrazide. Methyl 2-fluorobenzoate undergoes enzymatic dihydroxylation via the whole-cell fermentation in the presence of Escherichia coli JM109 (pDTG601A) to afford a diol. |
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