Identification | More | [Name]
Perfluorobutyl iodide | [CAS]
423-39-2 | [Synonyms]
1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE 1-IODONONAFLUOROBUTANE N-NONAFLUOROBUTYLIODIDE NONAFLUORO-1-IODOBUTANE NONAFLUOROBUTYL IODIDE NONAFLUORO-N-BUTYL IODIDE PERFLUOROBUTYL IODIDE PERFLUORO-N-BUTYL IODIDE 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-butan Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- m-Nonafluorobutyl iodide 1,1,2,2,3,3,4,4,4-Nonafluoro-1-iodobutane NONAFLUORO-1-IODOBUTANE, STAB. PERFLUOROBUTYL IODIDE 95% 1-Iodoperfluorobutane 1-Iodononafluorobutane,97% n-Nonafluorobutyliodide,98% 1-Iodononafluorobutane 98% 1-Iodononafluorobutane98% PERFLUOROBUTYL IODODE | [EINECS(EC#)]
207-025-8 | [Molecular Formula]
C4F9I | [MDL Number]
MFCD00001062 | [Molecular Weight]
345.93 | [MOL File]
423-39-2.mol |
Chemical Properties | Back Directory | [Appearance]
clear colourless liquid with pungent odour | [Melting point ]
-88 °C
| [Boiling point ]
66-67 °C
| [density ]
2.01 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.3285(lit.)
| [Fp ]
None | [storage temp. ]
0-6°C | [form ]
Liquid | [color ]
Clear purple | [Specific Gravity]
2.010 | [Stability:]
Stable. Incompatible with bases. | [Water Solubility ]
immiscible | [Sensitive ]
Light Sensitive | [BRN ]
1777546 | [Exposure limits]
ACGIH: TWA 0.01 ppm | [InChIKey]
PGRFXXCKHGIFSV-UHFFFAOYSA-N | [CAS DataBase Reference]
423-39-2(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Iodononafluorobutane(423-39-2) | [EPA Substance Registry System]
423-39-2(EPA Substance) |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
2810 | [WGK Germany ]
3
| [RTECS ]
EK5360000 | [F ]
8 | [Hazard Note ]
Irritant/Light Sensitive | [TSCA ]
T | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [HS Code ]
29034700 |
Hazard Information | Back Directory | [Description]
Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].
| [Chemical Properties]
clear colourless liquid with pungent odour | [Uses]
Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions. | [References]
[1] Darol Dodd, Colin Hardy, Gary Hoffman. "Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations. " International Journal of Toxicology 23 4 (2004): 249–58. [2] J. Lee, B. Tabibi, W. Weaver. "Perfluorobutyl iodides as gain media for a solar-pumped laser amplifier." Optics Communications 67 1 (1988): 435–440. [3] Zhang, Juan et al. "Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile?." RSC Advances 26 (2015): 20562–20565.
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