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42874-03-3

42874-03-3 Structure

42874-03-3 Structure
IdentificationMore
[Name]

Oxyfluorfen
[CAS]

42874-03-3
[Synonyms]

2-CHLORO-1-(3-ETHOXY-4-NITROPHENOXY)-4-(TRIFLUOROMETHYL)BENZENE
GALIGAN
GOAL
GOAL 2EC
GOALDATE
HADA F
KOLTAR
KOLTAR(R)
OXYFLUORFEN
OXYGOLD
RH-2915
2-Chloro-4-trifluoromethyl3’-ethoxy-4’-nitrodiphenylether
2-Chloro-alpha,alpha,alpha-trifluoro-p-tolyl-3-ethoxy-4-nitrophenyl ether
2-chloro-alpha,alpha,alpha-trifluoro-p-tolyl-3-ethoxy-4-nitrophenylether
Ether, 2-chloro-alpha,alpha,alpha-trifluoro-p-tolyl 3-ethoxy-4-nitrophenyl
ether,2-chloro-alpha,alpha,alpha-trifluoro-p-tolyl3-ethoxy-4-nitrophenyl
Oxyfluorfene
oxyfluorofen
Oxyflurofen
2-Chloro-1-(3-ethoxy-4-nitro phenoxy)-4-trioxy toluene
[EINECS(EC#)]

255-983-0
[Molecular Formula]

C15H11ClF3NO4
[MDL Number]

MFCD00072435
[Molecular Weight]

361.7
[MOL File]

42874-03-3.mol
Chemical PropertiesBack Directory
[Appearance]

Orange to deep redbrown crystalline solid or powder. Smoke-like odor.
[Melting point ]

83-84°C
[Boiling point ]

>240°C
[density ]

1.3500
[Fp ]

-18 °C
[storage temp. ]

APPROX 4°C
[solubility ]

DMSO : 100 mg/mL (276.47 mM; Need ultrasonic)
[form ]

Solid
[color ]

Orange crystal solid
[Water Solubility ]

117ug/L(temperature not stated)
[BRN ]

2065259
[InChIKey]

OQMBBFQZGJFLBU-UHFFFAOYSA-N
[LogP]

4.730
[CAS DataBase Reference]

42874-03-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)-(42874-03-3)
[EPA Substance Registry System]

42874-03-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xn,N
[Risk Statements ]

R11:Highly Flammable.
R38:Irritating to the skin.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R65:Harmful: May cause lung damage if swallowed.
R67:Vapors may cause drowsiness and dizziness.
[Safety Statements ]

S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
[RIDADR ]

UN 1145 3/PG 2
[WGK Germany ]

2
[RTECS ]

KN6900000
[Safety Profile]

When heated to decomposition emits toxic fumes of Cl-, F-, and NO2.
[Hazardous Substances Data]

42874-03-3(Hazardous Substances Data)
[Toxicity]

LD50 orally in male albino rats: >5000 mg/kg (Yih, Swithenbank)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Toluene-->Potassium hydroxide-->Bromoethane-->Resorcinol-->3,4-Dichlorobenzotrifluoride-->3,4-Dichlorotoluene-->Phenol, 3-[2-chloro-4-(trifluoromethyl)phenoxy]--->1,3-bis(2-chloro-4-(trifluoroMethyl)phenoxy)benzene-->5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenyl acetate-->3-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl acetate-->5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrophenol-->Oxyfluorfen IMpurity 2-->2,4-Dichloronitrobenzene-->Potassium ethylate
[Preparation Products]

Oxyfluorfen+Acetochlor,E.C.
Hazard InformationBack Directory
[General Description]

Orange crystalline solid. Non corrosive. Used as an herbicide.
[Reactivity Profile]

A trifluoromethyl diphenyl ether derivative.
[Air & Water Reactions]

Insoluble in water.
[Potential Exposure]

Oxyfluorfen, a diphenyl ether herbicide, is used for broad spectrum preemergence and postemergent control of annual broadleaf and grassy weeds in a variety of tree fruit, nut, vine, and field crops. The largest agricultural markets are wine grapes and almonds. Also used on ornamental and forestry sites. Oxyfluorfen is also used for weed control in landscapes, patios, driveways, and similar noncrop areas in residential, highway, and rights-ofway sites.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Do not induce vomiting when formulations containing petroleum solvents are ingested. Otherwise, give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Decomposes >330°C releasing toxic hydrogen fluoride, hydrogen chloride, and nitrogen oxides.
[Chemical Properties]

Orange to deep redbrown crystalline solid or powder. Smoke-like odor.
[Chemical Properties]

Pale Yellow Solid
[Waste Disposal]

Small quantities may be land filled but large quantities should be incinerated. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Herbicide.
[Uses]

Oxyfluorfen is a diphenyl ether broad spectrum herbicide. Oxyfluorfen is a pre- and post-emergent control broad leaf and grassy weeds in field crops.
[Definition]

ChEBI: Oxyfluorfen is an aromatic ether. It has a role as a herbicide and an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor.
[Agricultural Uses]

Herbicide: Oxyfluorfen is used for broad-spectrum pre-emergence and post-emergent control of annual broadleaf and grassy weeds in a variety of tree fruit, nut, vine, and field crops. The largest agricultural markets are wine grapes and almonds. Also used on ornamental and forestry sites. Oxyfluorfen is also used for weed control in landscapes, patios, driveways, and similar non-crop areas in residential, highway and rights-of-way sites. Not approved for use in EU countries. Registered for use in the U.S. and Canada
[Trade name]

EDGER®; FIRE POWER® (glyphosate + oxyfluorfen); GALIGAN®; GOAL®; HADAF®; KLEENUP®; KOLTAR®; MON-78095®; RH-2915®; RH-915®; ROUT® (with oryzalin); TRIOX®
[storage]

Store at -20°C
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Chloro-1-(3-ethoxy-4-nitrophenoxy)-4-(trifluoromethyl)benzene(42874-03-3).msds
Questions And AnswerBack Directory
[Description]

As a a diphenyl ether herbicide, Oxyfluorfen is a white to orange or red-brown crystalline solid with a smoke-like odor, which is used for broad-spectrum pre- and post-emergent control of annual broadleaf and grassy weeds in a variety of tree fruit, vegetables, fruit, cotton, nut, vine, and field crops. It belongs to the contact herbicide and requires light to impose killing effects on target plants. Besides, it can also be applied in non-agricultural ornamental and forestry, mainly used for weed control in landscapes, patios, driveways, and similar areas in residential sites.
[References]

http://pmep.cce.cornell.edu/profiles/extoxnet/metiram-propoxur/oxyfluorfen-ext.html
http://www.cngreenchem.com/pro_detail_en/id/19.html
https://www.fluoridealert.org/wp-content/pesticides/epage.oxyfluorfen.htm
Spectrum DetailBack Directory
[Spectrum Detail]

Oxyfluorfen(42874-03-3)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

42874-03-3(sigmaaldrich)
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