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488809-34-3

488809-34-3 Structure

488809-34-3 Structure
IdentificationBack Directory
[Name]

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
[CAS]

488809-34-3
[Synonyms]

(S)-[(RuCl(SEGPHOS®
(S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2]
(S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2]
[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(Cl)3]
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3]
[Molecular Formula]

(CH3)2NH2+[C76H56Cl5O8P4Ru2]−
[MDL Number]

MFCD09753037
[MOL File]

488809-34-3.mol
[Molecular Weight]

1650.69
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water
[form ]

Powder
[color ]

light brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS08
[Signal word ]

Danger
[Hazard statements ]

H373-H360-H371
[Precautionary statements ]

P260-P314-P501-P260-P264-P270-P309+P311-P405-P501
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Questions And AnswerBack Directory
[Reaction]

  1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. 
  2. Catalyst for enantioselective hydrogenation of enamines. 
Reactions of 488809-34-3
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
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