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944451-31-4

944451-31-4 Structure

944451-31-4 Structure
IdentificationBack Directory
[Name]

Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl
[CAS]

944451-31-4
[Synonyms]

(S)-RuCl[(p-cyMene)(DM-SEGPHOS)]Cl
[RuCl(p-cymene)((S)-dm-segphos[R])]Cl
[RuCl(p-cymene)((S)-dm-segphos(regR))]Cl
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl
Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dm-segphos(R))]Cl
[Molecular Formula]

C56H58Cl2O4P2Ru
[MDL Number]

MFCD09753018
[MOL File]

944451-31-4.mol
[Molecular Weight]

1026.98
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water
[form ]

Powder
[color ]

orange to brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Questions And AnswerBack Directory
[Reactions]

  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
Reactions of 944451-31-4
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
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