Identification | More | [Name]
D-(+)-MELEZITOSE | [CAS]
597-12-6 | [Synonyms]
D-(+)-MELEZITOSE D-MELEZITOSE MELEZITOSE O-ALPHA-D-GLUCOPYRANOSYL-(1-3)-BETA-D-FRUCTOFURANOSYL-ALPHA-D-GLUCOPYRANOSIDE alpha-d-glucopyranoside,o-alpha-d-glucopyranosyl-(1.fwdarw.3)-beta-d-fructo furanosyl melizitose D-MELEZITOSE MONOHYDRATE, FOR BACTERIOLOGY MELEZITOSE DIHYDRATE, D-(RG) D-MELZITOSE extrapure 3-O-α-D-Glucopyranosyl-β-D-fructofuranosyl α-D-glucopyranoside Melecitose | [EINECS(EC#)]
209-894-9 | [Molecular Formula]
C18H32O16 | [MDL Number]
MFCD00006627 | [Molecular Weight]
504.44 | [MOL File]
597-12-6.mol |
Chemical Properties | Back Directory | [Melting point ]
153°C | [Boiling point ]
513.84°C (rough estimate) | [density ]
1.5565 | [refractive index ]
88.5 ° (C=4, H2O) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Solid | [pka]
12.83±0.70(Predicted) | [color ]
White to off-white | [Water Solubility ]
Water : ≥ 31 mg/mL (61.45 mM) | [Merck ]
5819 | [LogP]
-5.790 (est) | [CAS DataBase Reference]
597-12-6(CAS DataBase Reference) | [EPA Substance Registry System]
Melezitose (597-12-6) |
Hazard Information | Back Directory | [Uses]
d-(+)-Melezitose can be used to treat cancer, autoimmune diseases and infectious diseases. | [Definition]
ChEBI: A trisaccharide produced by insects such as aphids. | [storage]
Store at -20°C | [Purification Methods]
D(+)-Melezitose crystallises from aqueous EtOH as the monohydrate and water as the dihydrate, and is then dried at 110o (anhydrous). It is also purified by dissolving in an equal volume of H2O, filtering into a crystallising dish and allowing to stand (loosely covered) for several weeks undisturbed at 20o. The crystals of clear prisms are wiped carefully and dried in air. They effloresce at once losing 3.35% of their weight, and after 3days in air the loss is for 1H2O from the dihydrate. Drying at 110o for 6hours in vacuo yields the anhydrous form which after 2days in air it absorbs H2O to give the monohydrate. The monohydrate is also obtained by dissolving it in an equal weight of H2O at 60o and adding 4 volumes of 95% EtOH and drying in air overnight. [Richtmeyer & Hudson J Org Chem 11 610 1946, Beilstein 17 III/IV 3815, 17/8 V 414.] |
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