ChemicalBook--->CAS DataBase List--->602-87-9

602-87-9

602-87-9 Structure

602-87-9 Structure
IdentificationMore
[Name]

5-NITROACENAPHTHENE
[CAS]

602-87-9
[Synonyms]

5-NITROACENAPHTHENE
Nitroacenaphthene
1,2-dihydro-5-nitro-acenaphthylen
1,2-dihydro-5-nitroacenaphthylene
1,2-Dihydro-5-nitro-acenaphthylene
5-Nan
5-Nitro-1,2-dihydroacenaphthylene
5-nitro-acenaphthen
5-Nitroacenapthene
5-Nitronaphthalene ethylene
5-nitronaphthaleneethylene
Acenaphthene, 5-nitro-
Acenaphthylene, 1,2-dihydro-5-nitro-
NCI-C01967
5-Nitroacenaphthene,tech.85%
5-Nitroacenaphthene (contains 3-Nitroacenaphthene)
5-Nitroacenaphthene, tech. 85%
[EINECS(EC#)]

210-025-0
[Molecular Formula]

C12H9NO2
[MDL Number]

MFCD00014277
[Molecular Weight]

199.21
[MOL File]

602-87-9.mol
Chemical PropertiesBack Directory
[Appearance]

5-Nitroacenaphthene is a yellow crystalline solid.
[Melting point ]

100-101 °C(lit.)
[Boiling point ]

279°C
[density ]

1.1919 (rough estimate)
[refractive index ]

1.5880 (estimate)
[Fp ]

279°C
[storage temp. ]

-20°C Freezer
[solubility ]

Chloroform (Slightly), DMSO (Slightly)
[form ]

Solid
[color ]

Light Yellow to Yellow
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[BRN ]

1876864
[CAS DataBase Reference]

602-87-9(CAS DataBase Reference)
[IARC]

2B (Vol. 16, Sup 7) 1987
[EPA Substance Registry System]

5-Nitroacenaphthene (602-87-9)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R45:May cause cancer.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

2811
[WGK Germany ]

3
[RTECS ]

AB1060000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29049090
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
[Hazardous Substances Data]

602-87-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acenaphthene
[Preparation Products]

4-Nitro-1,8-Naphthalenedicarboxylic Acid-->4-Nitronaphthalene-1,8-dicarboxylic anhydride
Hazard InformationBack Directory
[General Description]

Yellow powder.
[Reactivity Profile]

Aromatic nitro compounds, such as 5-NITROACENAPHTHENE(602-87-9), range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
[Air & Water Reactions]

Insoluble in water.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: There is clear evidence that this compound is an animal carcinogen. When heated to decomposition it emits toxic fumes of NOx.
[Potential Exposure]

Used in organic synthesis.
[Fire Hazard]

Flash point data for this chemical are not available. 5-NITROACENAPHTHENE is probably combustible.
[First aid]

Skin Contact: Flood all areas of body that have contacted the substance with water. Don’t wait to remove contaminated clothing; do it under the water stream. Use soap to help assure removal. Isolate contaminated clothing when removed to prevent contact by others. Eye Contact: Remove any contact lenses at once. Flush eyes well with copious quantities of water or normal saline for at least 20 30 minutes. Seek medical attention. Inhalation: Leave contaminated area immediately; breathe fresh air. Proper respiratory protection must be supplied to any rescuers. If coughing, difficult breathing or any other symptoms develop, seek medical attention at once, even if symptoms develop many hours after exposure. Ingestion: If convulsions are not present, give a glass or two of water or milk to dilute the substance. Assure that the person’s airway is unobstructed and contact a hospital or poison center immediately for advice on whether or not to induce vomiting.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

5-Nitroacenaphthene is an aromatic hydrocarbon (nitro compound). It may be flammable or explosive. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides; alkalis may increases the thermal sensitivity of this chemical.
[Chemical Properties]

5-Nitroacenaphthene is a yellow crystalline solid.
[Chemical Properties]

yellow powder
[Waste Disposal]

Careful incineration in an incinerator equipped with afterburner and scrubbers.
[Uses]

5-Nitroacenaphthene is a derivative of acenaphthene, a polycyclic hydrocarbon that has potential to act as polyploidizing agents in plants.
[Definition]

ChEBI: 5-Nitroacenaphthene is a nitronaphthalene.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

nitroacenaphthene(602-87-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

5-NITROACENAPHTHENE(602-87-9)MS
5-NITROACENAPHTHENE(602-87-9)IR1
5-NITROACENAPHTHENE(602-87-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

5-Nitroacenaphthene, 98%(602-87-9)
[Sigma Aldrich]

602-87-9(sigmaaldrich)
[TCI AMERICA]

5-Nitroacenaphthene  (contains 3-Nitroacenaphthene),>80.0%(GC)(602-87-9)
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