Identification | More | [Name]
Diphenic anhydride | [CAS]
6050-13-1 | [Synonyms]
2,2'-BIBENZOIC ANHYDRIDE 2,2'-BIPHENYLDICARBOXYLIC ACID ANHYDRIDE 2,2'-BIPHENYLDICARBOXYLIC ANHYDRIDE 2,2'-DIPHENIC ANHYDRIDE DIPHENIC ANHYDRIDE O-DIPHENIC ANHYDRIDE dibenz[c,e]oxepin-5,7-dione diphenic acid anhydride biphenyl-2,2'-dicarboxylic anhydride Diphenicanhydride,98% 2,2'-Diphenyldicarboxylic anhydride Benzo[d][2]benzoxepine-5,7-dione 1,1'-Biphenyl-2,2'-dicarboxylic anhydride Dibenz[c,e]oxepine-5,7-dione | [EINECS(EC#)]
227-950-0 | [Molecular Formula]
C14H8O3 | [MDL Number]
MFCD00004993 | [Molecular Weight]
224.21 | [MOL File]
6050-13-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S37/39:Wear suitable gloves and eye/face protection . S7/8:Keep container tightly closed and dry . S24/25:Avoid contact with skin and eyes . S37:Wear suitable gloves . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29173990 |
Hazard Information | Back Directory | [Chemical Properties]
Powder | [Purification Methods]
After removing free acid by extraction with cold aqueous Na2CO3, the residue is crystallised from acetic anhydride and dried at 100o. Acetic anhydride converts the acid to the anhydride. It also crystallises from *C6H6 (m 219o) or chlorobenzene (m 224.5-225.5o). [Beilstein 17 H 526, 17 II 495, 17 III/IV 6425.] |
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