Identification | More | [Name]
(+)-Dimethyl L-tartrate | [CAS]
608-68-4 | [Synonyms]
(2R,3R)-2,3-DIHYDROXY-SUCCINIC ACID DIMETHYL ESTER (2R,3R)-(+)-DIMETHYL TARTRATE DIMETHYL (2R,3R)-DIHYDROXYSUCCINATE (+)-DIMETHYL L-TARTRATE DIMETHYL L-(+)-TARTRATE DIMETHYL L-TARTRATE DIMETHYL-L-TARTRATE, (+)- (+)-DIMETHYL TARTRATE L(+)-DIMETHYL TARTRATE L-DMT (+)-L-TARTARIC ACID DIMETHYL ESTER L-(+)-TARTARIC ACID DIMETHYL ESTER (+)-TARTARIC ACID DIMETHYL ESTER 2,3-dihydroxy-[theta-(theta,theta)]-butanedioicacidimethylester DimethylL-(+)-tartarate Lg-tartaricaciddimethylester Dimethyl-L-(+)-Tartratic L-plus-tartaric acid dimethyl ester dimethyl [R(R*,R*)]-tartrate Dimethyl-L-(+)-Tartratic Acid | [EINECS(EC#)]
210-166-8 | [Molecular Formula]
C6H10O6 | [MDL Number]
MFCD00064437 | [Molecular Weight]
178.14 | [MOL File]
608-68-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . S36/37:Wear suitable protective clothing and gloves . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29181300 |
Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
(+)-Dimethyl L-tartrate is used as a starting reagent in the synthesis of (+)-Monomorine I, a pyrrolidine-based alkaloid that is a trail pheromone of the Pharaoh’s ant (Monomorium pharaonis). | [Uses]
(+)-Dimethyl L-tartrate can react with sulfur tetrafluoride to form dimethyl meso-2,3-difluorosuccinate. It may be used in the synthesis of the following chiral ligands for use in asymmetric synthesis:
- (2R, 3R)-1,4-dimethoxy-1,1,4,4-tetraphenyl-2,3-butanediol
- (-)-(4S,5R)-4-(2-pyridyl)-5-(diphenylphosphino)methyl-2,2-dimethyl-1,3-dioxolane (PYDIPHOS)
- (4R,5R)-α,α,α′,α′-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane
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